U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Electrochemical capacitor and method of use

Patent 7292431 Issued on November 6, 2007. Estimated Expiration Date: Icon_subject April 4, 2025. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

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Patent #: 5948562
Issued on: 09/07/1999
Inventor: Fulcher, et al.

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Patent #: 5968745
Issued on: 10/19/1999
Inventor: Thorp, et al.

Conducting polymer transition metal hybrid materials and sensors
Patent #: 6323309
Issued on: 11/27/2001
Inventor: Swager, et al.

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Patent #: 6414837
Issued on: 07/02/2002
Inventor: Sato, et al.

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Patent #: 6426863
Issued on: 07/30/2002
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Electric double-layer capacitor and carbon material therefor
Patent #: 6721168
Issued on: 04/13/2004
Inventor: Takeuchi, et al.

Electrochemical capacitor and methods of fabricating same Patent #: 6758868
Issued on: 07/06/2004
Inventor: Munshi

Inventors

Assignee

Application

No. 11098698 filed on 04/04/2005

US Classes:

361/502, Double layer electrolytic capacitor361/503, Liquid electrolytic capacitor361/504, With significant electrolyte361/508, Anode type electrode361/512, With separator361/525, With significant electrolyte or semiconductor361/527, Organic salt (e.g., TCNQ)29/25.03, Electrolytic device making (e.g., capacitor)429/181, And terminal seal435/6, Involving nucleic acid205/58Organic active material other than organic metal salt

Examiners

Primary: Ha, Nguyen T.

Attorney, Agent or Firm

International Class

H01G 9/00

Abstract

The invention is an electrochemical capacitor with its electrodes made on a conducting substrate with a layer of a redox polymer of the poly[Me(R-Salen)] type deposited onto the substrate. Me is a transition metal (for example, Ni, Pd, Co, Cu, Fe), R is an electron-donating substituent (for example, CH3O—, C2H5O—, HO—, —CH3), Salen is a residue of bis(salicylaldehyde)-ethylendiamine in Schiff's base. The electrolyte comprises of an organic solvent, compounds capable of dissolving in such solvents with the resulting concentration of no less than 0.01 mol/l and dissociating with the formation of ions, which are electrochemically inactive within the range of potentials from −3.0 V to +1.5 V (for example, salts of tetramethyl ammonium, tetrapropyl ammonium, tetrabutyl ammonium), and a dissolved metal complex [Me(R-Salen)]. The method of using the capacitor contemplates periodically alternating the connection polarity of the electrodes, causing the electrochemical characteristics of the electrodes to regenerate.

Other References

  • P. Audebert, et al., “Electrochemical polymerization of several salen-type complexes. Kinetic studies in the microsecond time range”. J. Electroanal. Chem., 338 (1992) pp. 269-278, XP009026799.
  • Lanqun Mao, et al., “A New Ultramicrosensor for Nitric Oxide Based on Electropolymerized Film of Nickel Salen”, Analytical Letters, 31(12), pp. 1991-2007 (1998), XP009026797.
  • Magda Martins, et al., “Ni(Salen)-based Polymer Modified Electrodes as Sensor for Metal Ions”, Electrochemical Society Proceedings, vol. 2001-18, pp. 399-407, XP009024792.
  • Colin P. Horwitz, et al., “Oxidative Electropolymerization of Metal Schiff-Base Complexes”, Mol. cryst. Liq. Cryst., 1988, vol. 160, pp. 389-404, XP009024770.
  • P. Audebert, et al., “Redox and Conducting Polymers Based on Salen-Type Metal Units; Electrochemical Study and Some Characteristics”, New Journal of Chemistry, vol. 16, 1992, pp. 697-703, XP001179208.
  • Fethi Bedioui, et al., “Electrooxidative polymerization of cobalt, nickel and manganese salen complexes in acetonitrile solution”, 1991-Elsevier Sequoia S.A., pp. 267-274, XP009024767.
  • Lisa A. Hoferkamp, et al., “Surface-Modified Electrodes Based on Nickel (II) and Copper (II) Bis(salicylaldimine) Complexes”, 1989 American Chemical Society, pp. 348-352, XP009024771.
  • Lanqun Mao, et al., “Electrochemical Nitric Oxide Sensors Based on Electropolymerized Film of M(salen) with Central Ions of Fe, Co, Cu, and Mn”, pp. 72-77, XP009024739.
  • Guo-dong Liu, et al., “Electro-catalytic oxidation of ascorbic acid at a cobalt-salen polymer modified electrode and analytical applications”, pp. 175-192, XP009024738.
  • A. Alatorre Ordaz, et al., “Electrocatalysis of the reduction of organic halide derivatives at modified electrodes coated by cobalt and iron macrocyclic complex-based films: application to the electrochemical determination of pollutants”, EDP Sciences, Wiley-VCH 2000, pp. 238-244, XP009024693.
  • Jerry L. Reddinger, et al., “A Novel Polymeric Metallomacrocycle Sensor Capable of Dual-Ion Cocomplexation”, 1998 American Chemical Society, pp. 3-5, XP009024677.
  • Jerry L. Reddinger, et al., “Site Specific Electropolymerization to Form Transition-Metal-Containing, Electroactive Polythiophenes”, 1998 American Chemical Society, pp. 1236-1243, XP009024632.
  • Jerry L. Reddinger, et al., “Tunable Redox and Optical Properties Using Transition Metal-Complexed Polythiophenes”, 1997 American Chemical Society, pp. 673-675, XP 000678019.
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