U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Carbon nanotube product comprising single-walled carbon nanotubes

Patent 6994907 Issued on February 7, 2006. Estimated Expiration Date: Icon_subject April 25, 2023. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3746657

Catalysts for producing alcohols from olefins and synthesis gas
Patent #: 4456694
Issued on: 06/26/1984
Inventor: Blaskie ,   et al.

Method for preparing high activity silica supported hydrotreating catalysts
Patent #: 4574120
Issued on: 03/04/1986
Inventor: Thompson

Carbon fibrils, method for producing same and compositions containing same
Patent #: 4663230
Issued on: 05/05/1987
Inventor: Tennent

Carbon fibrils and method for producing same
Patent #: 5165909
Issued on: 11/24/1992
Inventor: Tennent, et al.

Electric arc process for making fullerenes
Patent #: 5227038
Issued on: 07/13/1993
Inventor: Smalley, et al.

Process for making fullerenes by the laser evaporation of carbon
Patent #: 5300203
Issued on: 04/05/1994
Inventor: Smalley

Process for producing acetic acid
Patent #: 5405996
Issued on: 04/11/1995
Inventor: Suzuki, et al.

Method and device for the production of carbon nanotubes
Patent #: 5482601
Issued on: 01/09/1996
Inventor: Ohshima, et al.

Carbon nanostructures encapsulating palladium
Patent #: 5543378
Issued on: 08/06/1996
Inventor: Wang

More ...

Inventors

Assignee

Application

No. 10423687 filed on 04/25/2003

US Classes:

428/367, Including free carbon or carbide or therewith (not as steel)204/173, Carbon502/174, Inorganic carbon containing423/461, Recovery or purification502/180, Elemental carbon423/210, MODIFYING OR REMOVING COMPONENT OF NORMALLY GASEOUS MIXTURE502/416, Free carbon containing428/364, Rod, strand, filament or fiber427/216, Metal base423/344, Binary compound (e.g., silicide, etc.)428/408, SELF-SUSTAINING CARBON MASS OR LAYER WITH IMPREGNANT OR OTHER LAYER423/249, RADIOACTIVE (AT. NO. 84+ OR RADIOACTIVE ISOTOPE OF ANOTHER ELEMENT)423/447.3From gaseous reactants

Examiners

Primary: Hendrickson, Stuart L.

Attorney, Agent or Firm

Foreign Patent References

  • 9709272 WO 03/01/1997
  • 98392550 WO 09/01/1998
  • 9842620 WO 10/01/1998
  • WO 00/17102 WO 03/01/2000
  • PCT/US00/15362 WO 06/01/2000
  • 0073205 WO 07/01/2000
  • PCT/US02/23155 WO 07/01/2003

International Class

D01F 9/12

Abstract

A carbon nanotube product formed from a metallic catalytic particle and single-walled carbon nanotubes deposited thereon. The catalytic particles preferably contain at least one metal from Group VIII, including for example Co, Ni, Ru, Rh, Pd, Ir, and Pt, and at least one metal from Group VIb including for example Mo, W and Cr. The metallic catalytic particle preferably further comprises a support material such as silica. The carbon nanotube product is preferably formed by exposing the metallic catalytic particle to a carbon-containing gas at a temperature sufficient to form the single-walled nanotubes as a primary portion of a solid carbon product on the metallic catalytic particles.

Other References

  • Alvarez, et al., “Synergism of Co and Mo in the catalytic production of single-wall carbon nanotubes by decomposition of CO”, Elsevier Science Ltd., Carbon 39 (2001), pp. 547-558.
  • Bandow et al., “Effect of the Growth Temperature on the Diameter Distribution and Chirality of Single-Wall Carbon Nanotubes”, The American Physical Society, Physical Review Letters, vol. 80, No. 17, (1998), pp. 3779-3782.
  • De Boer et al., “The cobalt-molybdenum interaction in CoMo/SiO2 catalysts: A CO-oxidation study”, Elsevier Science Ltd., Solid State Ionics 63-65 (1993), pp. 736-742.
  • Bethune et al.; “Cobalt-Catalysed Growth of Carbon Nanotubes with Single-Atomic-Layer Walls,” Nature, 363:605-607, Jun. 1993.
  • V. Brotons et al., “Catalytic influence of bimetallic phases for the synthesis of single-walled carbon nanotubes”, Journal of Molecular Catalysis, A: Chemical 116 (1997) 397-403.
  • Cassell et al., “Large Scale CVD Synthesis of Single-Walled Carbon Nanotubes”, American Chemical Society, pp. 6483-6492, 1999.
  • Che et al., “Chemical Vapor Deposition Based Synthesis of Carbon Nanotubes and Nanofibers Using a Template Method”, Chemical Mater. 1998, 10, pp. 260-267.
  • Chen et al., “Growth of carbon nanotubes by catalytic decompositon of CH4 or CO on a Ni-MgO catalyst”, CARBON vol. 35, No. 10-11, pp. 1495-1501, 1997.
  • Cheng et al.; “Bulk Morphology and Diameter Distribution of Single-Walled Carbon Nanotubes Synthesized by Catalytic Decomposition of Hydrocarbons,” Chemical Physics Letters, 289:602-610, 1998.
  • Cheng et al.; “Large-Scale and Low-Cost Synthesis of Single-Walled Carbon Nanotubes by the Catalytic Pyrolysis of Hydrocarbons,” Applied Physics Letters, 72 (25): 3282-3284, Jun. 25, 1998.
  • Dai et al.; “Single-Wall Nanotubes Produced by Metal-Catalyzed Disproportionation of Carbon Monoxide,” Chemical Physics Letters, 260: 471-475, 1996.
  • Database, Accession No. 1999-366878, Cano, “Canno KK”, XP-002149235, May 25, 1999.
  • Fonseca et al., “Synthesis of single-and multi-wall carbon nanotubes over supported catalysts”, Applied Physics A, 67, pp. 11-22, 1998.
  • Govindaraj et al., “Carbon structures obtained by the disproportionation of carbon monoxide over nickel catalysts”, Materials Research Bulletin, vol. 33, No. 4, pp. 663-667, 1998.
  • Hafner et al., “Catalytic growth of single-wall carbon nanotubes from metal particles”, Chemical Physics Letters, 296, pp 195-202, 1998.
  • Hernadi et al., “Catalytic synthesis of carbon nanotubes using zeolite support”, Elsevier Science Inc. 1996.
  • Hyperion Catalysis International Website; http://www.fibrils.com/esd.htm; “Unique Slough Resistant SR™ Series ESD Thermoplastic Product Line Offers Reduced Particle Contamination For Demanding Electronic Applications,” and Hyperion Homepage http://www.fibrils.com.
  • I. Willems et al., “Control of the outer diameter of thin carbon nanotubes synthesized by catalytic decomposition of hydrocarbons”, Chemical Physics Letters, 317 (2000) pp. 71-76.
  • Iijima, Sumio; “Helical Microtubules of Graphitic Carbon,” Nature, 354:56-58, Nov. 1991.
  • Iijima et al.; “Single-Shell Carbon Nanotubes of 1-nm Diameter”, Nature 363:603-605, Jun. 1993.
  • Ivanov et al.; “The Study of Carbon Nanotubes Produced by Catalytic Method,” Chemical Physics Lettersm 223:329-335, 1994.
  • Jourent et al.; “Large-Scale Production of Single-Walled Carbon Nanotubes by the Electric-Arc Technique,” Nature, 338:756-758, Aug. 1997.
  • B. Kitiyanan et al., “Controlled production of single-wall carbon nanotubes by catalytic decomposition of CO on bimetallic Co-Mo catlaysts”, Chemical Physics Letters, 317 (2000), pp. 497-503, Feb. 4, 2000.
  • Krishnankutty et al., “The Effect of Copper on the Structural Characteristics of Carbon Filaments Produced from Iron Catalyzed Decomposition of Ethylene,” Catalysts Today, 37:295-307, 1997.
  • Li et al., “Large-Scale Synthesis of Aligned Carbon Nanotubes”, SCIENCE, vol. 274, pp. 1701-1703.
  • Rinzler et al.; “Large-Scale Purification of Single-Wall Carbon Nanotubes: Process, Product, and Characterization,” Applied Physics A, 67:29-37, 1998.
  • Thess et al., Crystalline Ropes of Metallic Carbon Nanotubes, SCIENCE , vol. 273, pp. 483-487.
  • Yakobson et al., “Fullerene Nanotubes: C 1.000,000 and Beyond,” American Scientist, 85:324-337, Jul.-Aug. 1997.
PatentsPlus Images
Enhanced PDF formats
loading...
PatentsPlus: add to cart
PatentsPlus: add to cartSearch-enhanced full patent PDF image
$9.95more info
 
Sign InRegister
Username  
Password   
forgot password?