U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Process for quantitatively converting urea to ammonia on demand

Patent 6761868 Issued on July 13, 2004. Estimated Expiration Date: Icon_subject September 12, 2021. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3826815

3900554

3922222

Method of hydrolyzing urea contained in waste water streams
Patent #: 4087513
Issued on: 05/02/1978
Inventor: Schell

Catalytic method for hydrolyzing urea
Patent #: 4168299
Issued on: 09/18/1979
Inventor: Schell

Urea reduction of NOx in combustion effluents
Patent #: 4208386
Issued on: 06/17/1980
Inventor: Arand ,   et al.

Reduction of nitrogen oxides with catalytic acid resistant aluminosilicate molecular sieves and ammonia
Patent #: 4220632
Issued on: 09/02/1980
Inventor: Pence ,   et al.

Catalytic method for hydrolyzing urea
Patent #: 4220635
Issued on: 09/02/1980
Inventor: Schell

Process for the purification of urea solutions containing biuret and the like
Patent #: 4231960
Issued on: 11/04/1980
Inventor: Schmidt

Process for purifying urea-containing waste water and process for preparing melamine
Patent #: 4308385
Issued on: 12/29/1981
Inventor: Goorden

More ...

Inventors

Assignee

Application

No. 09951287 filed on 09/12/2001

US Classes:

423/358, From organic material containing nitrogen423/235Nitrogen or nitrogenous component

Examiners

Primary: Langel, Wayne A.

Attorney, Agent or Firm

Foreign Patent References

  • 0154 442 DE 03/01/1982
  • 342 21 75 DE 12/01/1985
  • 195 10 804 DE 09/01/1996
  • 195 81 575 DE 04/01/1997
  • 198 34 980 DE 12/01/1999
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  • 0 342 184 EP 11/01/1989
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  • 0 582 022 EP 02/01/1994
  • 0 848 985 EP 06/01/1998
  • 0 738 179 EP 04/01/1999
  • 1 019 321 EP 07/01/2000
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  • 1103041 GB 02/01/1968
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  • WO 9509810 WO 04/01/1995
  • WO 9606674 WO 03/01/1996
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  • WO 9842623 WO 10/01/1998
  • WO 9961136 WO 12/01/1999
  • WO 0007695 WO 12/01/2000

International Class

C01C 108

Abstract

Processes and apparatus for quantitatively converting urea to ammonia on demand are disclosed. One process includes the steps of: receiving a demand rate signal for ammonia; feeding reactants including urea and water into a reactor to provide a reaction mixture; and controlling temperature and pressure in the reactor to produce a gaseous product stream including ammonia and carbon dioxide at substantially constant concentrations. Another process includes the steps of: feeding molten urea or solid urea to a reactor; feeding water (liquid or steam) to the reactor; and reacting the urea and water at elevated temperature and pressure to form a gaseous product stream including ammonia and carbon dioxide.

Other References

  • Kucheryavyi et al.; “Kinetics of the Hydrolysis of Urea at High Temperatures in Relation to Purification of Waste Waters in Urea Manufacture”; translated from Zhurnal Prikladnoi Khimii, vol. 42, No. 7, pp. 1596-1600 (1969), (no month).
  • Blasiak et al.; “Equilibrium Pressure in the System NH4CO2NH2 + H2O at High Temperatures”; Chemia Stosowana, vol. 4, No. 545, pp. 545-550 (1983), (no month).
  • Makansi, Jason Ed.; “Ammonia: It's coming to a plant near you”; Power pp. 20-22 (May, 1992), (no month).
  • Smith et al.; “Integrated Dry NOx/SOx Emissions Control System Low-NOx Combustion System SNCR Test Report,” Public Service Company of Colorado, DOE Contract No. DE-FC22-91 PC 90550 (Jun. 1994).
  • International Preliminary Examination Report (PCT) Application No. PCT/US98/05708 dated May 11, 1999, believed to be publicly available Oct., 1999.
  • Hunt et al.; “Selective Non-Catalytic Operating Experience Using Both Urea and Ammonia” 1993 Joint Symposium on Stationary Combustion NOx, Control (May 1993).
  • Dr.-Ing. Ulrich Neurmann; “Drei trockene Typen Das DENOX-Verfahren von Hitachi”;(Three Dry Types—The DeNOx Process from Hitachi), Energie (Apr., 1986).
  • International Search Report for PCT/US02/09294 mailed Aug. 7, 2002.
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