U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

High efficiency transparent organic light emitting devices

Patent 6639357 Issued on October 28, 2003. Estimated Expiration Date: Icon_subject March 9, 2020. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Multilayer organic photovoltaic elements
Patent #: 4164431
Issued on: 08/14/1979
Inventor: Tang

Devices formed utilizing organic materials
Patent #: 4611385
Issued on: 09/16/1986
Inventor: Forrest ,   et al.

Electroluminescent device with organic luminescent medium
Patent #: 4720432
Issued on: 01/19/1988
Inventor: VanSlyke ,   et al.

Organic electroluminescent device with stabilized cathode
Patent #: 5047687
Issued on: 09/10/1991
Inventor: VanSlyke

Electroluminescent device with improved cathode
Patent #: 5059862
Issued on: 10/22/1991
Inventor: VanSlyke, et al.

Organic optoelectronic devices and methods
Patent #: 5315129
Issued on: 05/24/1994
Inventor: Forrest, et al.

Organic electroluminescent device
Patent #: 5399936
Issued on: 03/21/1995
Inventor: Namiki, et al.

Method and apparatus using organic vapor phase deposition for the growth of organic thin films with large optical non-linearities
Patent #: 5554220
Issued on: 09/10/1996
Inventor: Forrest, et al.

Bilayer electrode on a n-type semiconductor
Patent #: 5677572
Issued on: 10/14/1997
Inventor: Hung, et al.

Transparent contacts for organic devices
Patent #: 5703436
Issued on: 12/30/1997
Inventor: Forrest, et al.

More ...

Inventors

Assignee

Application

No. 09/522155 filed on 03/09/2000

US Classes:

313/504, Organic phosphor257/E51.042, Phthalocyanine (EPO)257/E51.043, Metal complexes comprising Group IIIB metal (Al, Ga, In, or Ti) (e.g., Tris (8-hydroxyquinoline) aluminium (Alq3)) (EPO)313/506Plural layers

Examiners

Primary: Patel, Ashok
Assistant: Guharay, Karabi

Attorney, Agent or Firm

International Classes

H01L 51/50 (20060101)
H01L 51/52 (20060101)
H01L 51/05 (20060101)
H01L 51/30 (20060101)

Abstract

A highly transparent non-metallic cathode is disclosed that comprises a metal-doped organic electron injection layer that is in direct contact with a transparent non-metallic electron injecting cathode layer, such as indium tin oxide (ITO), wherein the metal-doped organic electron injection layer also functions as an exciton blocking or hole blocking layer. The metal-doped organic electron injection layer is created by diffusing an ultra-thin layer of about 5-10 Å of a highly electropositive metal such as Li throughout the layer. A representative embodiment of the highly transparent non-metallic cathode comprises a layer of ITO, a layer of 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP), which acts as an electron injection, exciton blocking, and hole blocking layer, and an ultra-thin layer of lithium, which degenerately dopes the layer of BCP, improving the electron injecting properties of the BCP layer. This cathode is demonstrated for use in an OLED having a transparency of about 90% or higher combined with a device external quantum efficiency of about 1% or higher.

Other References

  • CW. Tang, et al., "Organic Electroluminescent Diodes", 51 Appl. Phys. Lett., 913 (1987). (Sep.)
  • S.R. Forrest, et al., "Organic Emitters Promise a New Generation of Displays", Laser Focus World, (Feb. 1995)
  • V. Bulovic, et al.,"Transparent light-emitting devices" Nature, 380, p. 29 (1996). (Mar.)
  • Z. Shen, et al. "Three-Color, Tunable, Organic Light-Emitting Devices", Science, 276, pp. 2009-2011 (1997). (Jun.)
  • G. Parthasarathy, et al.,"Metal-free cathode for organic semiconductor devices", Appl. Phys. Lett., 72, pp. 2138-2140 (1998). (Apr.)
  • J. Kido, et al., "Bright organic electroluminescent devices having a metal-doped electron-injecting layer", Applied Physics Letters, v. 73, n.20, pp. 2866-2868 (1998). (Nov.)
  • L.S. Hung, et al., "Interface engineering in preparation of organic surface-emitting diodes", Applied Physics Letters, v.74, n.21, pp. 3209-3211 (1999). (May)
  • N. Johansson, et al., "Electronic structure of tris (8-hydroxyquinoline) aluminum thin films in the pristine and reduced states", J. Chem. Phys., 111, pp. 2157-2163 (1999). (Aug.)
  • G. Gu, et al., "Transparent stacked organic light emitting devices", J. Appl. Phys., 86, pp. 4067-4075 (1999). (Oct.)
  • P. E. Burrows, et al., "Relationship between electroluminescence and current transport in organic heterojunction light-emitting devices", J. Appl. Phys. ,79, pp. 7991-8006 (1996). (May)
  • G. Parthasarathy, et al., "A full color transparent metal-free stacked organic light emitting device with simplified pixel biasing", Adv. Mat. , 11, pp. 907-910 (1999). (No month)
  • E.I. Haskal, et al., "Lithium-aluminum contacts for organic-light emitting devices", Appl. Phys. Lett., 71, pp. 1151-1153 (Sep. 1, 1997)
  • Parthasarathy, et al., "A Highly Transparent Organic Light Emitting Device Employing a Metal-Free Cathode," Poster Session Abstract, Materials Research Fair, Princeton Materials Institute, Princeton University (Nov. 6, 1997)
  • Kido, et al., "Bright red light-emitting organic electroluminescent devices having a europium complex as an emitter," Appl. Phys. Lett., v.65 (1994) pp. 2124-2126. (Oct.)
  • Kido, et al., "White-light-emitting organic electroluminescent device using lanthanide complexes," Jpn. J. Appl. Phys., v.35 (1996) pp. L394-L396. (Mar.)
  • Kido, et al., "Multilayer white light-emitting organic electroluminescent device," Science, v.267 (1995) pp. 1332. (Mar.)
  • Kido, et al., "Electroluminescence in terbium complex," Chemistry Letters (1990) pp. 657-660. (No month)
  • Kido and K. Nagai, "Organic Electroluminescent Devices Using Lanthanide Complexes," Journal of Alloys and Compounds, vol. 192 (1993) pp. 30-33. (No month)
  • Hung, et al., "Enhanced electron injection in organic electroluminescence devices using an Al/LiF electrode," Appl. Phys. Lett. 70 (1997) pp. 152. (Jan.)
  • Forrest, et al., "Organic-on-inorganic semiconductor contact barrier diodes . . . ," J. Appl. Phys. 56 (1984) pp. 543. (Jul.)
  • Bulovic, et al., "Study of locilized and extended excitons in 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) . . . ," Chem. Phys. 210 (1996) pp. 1-12. (No month)
  • Co-pending application Ser. No. 09/153,144, filed Sep. 14, 1998, entitled "Structure for High Efficiency Electroluminescent Device". (Now U.S. patent no. 6,097,147)
PatentsPlus Images
Enhanced PDF formats
loading...
PatentsPlus: add to cart
PatentsPlus: add to cartSearch-enhanced full patent PDF image
$9.95more info
PatentsPlus: add to cart
PatentsPlus: add to cartIntelligent turbocharged patent PDFs with marked up images
$16.95more info
 
Sign InRegister
Username  
Password   
forgot password?