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Production of a GaN bulk crystal substrate and a semiconductor device formed on a GaN bulk crystal substrate

Patent 6592663 Issued on July 15, 2003. Estimated Expiration Date: Icon_subject June 8, 2020. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Low temperature method of preparing GaN single crystals
Patent #: 5868837
Issued on: 02/09/1999
Inventor: DiSalvo, et al.

Process for preparing bulk cubic gallium nitride
Patent #: 6177057
Issued on: 01/23/2001
Inventor: Purdy

Method of fabricating nitride crystal, mixture, liquid phase growth method, nitride crystal, nitride crystal powders, and vapor phase growth method Patent #: 6270569
Issued on: 08/07/2001
Inventor: Shibata, et al.

Inventors

Assignee

Application

No. 590063 filed on 06/08/2000

US Classes:

117/68, Having growth from a solution comprising a solvent which is liquid at or below 20 degrees Celsius (e.g., aqueous solution)117/13, Having pulling during growth (e.g., Czochralski method, zone drawing)117/73, Havin growth from molten state (e.g., solution melt)117/74, Including change in a growth-influencing parameter (e.g., composition, temperature, concentration, flow rate) during growth (e.g., multilayer or junction or superlattice growing)117/75, Forming a platelet shape or a small diameter, elongate, generally cylindrical shape (e.g., whisker, fiber, needle, filament) (e.g., VLS method)117/77, Gas or vapor state precursor or overpressure117/78, Precursor composition intentionally different from product (e.g., excess component, non-product forming component, dopant, non-stoichiometric precursor, solvent, flux)117/223, Shape defined by a solid member other than seed or product (e.g., Bridgman-Stockbarger)117/224, Including pressurized crystallization means (e.g., hydrothermal)117/952Nitride containing (e.g., GaN, cBN) {C30B 29/38}

Examiners

Primary: Kunemund, Robert

Attorney, Agent or Firm

International Classes

C30B 011/04
C30B 011/12

Foreign Application Priority Data

1999-06-09 JP

Abstract

A method of making a bulk crystal substrate of a GaN single crystal includes the steps of forming a molten flux of an alkali metal in a reaction vessel and causing a growth of a GaN single crystal from the molten flux, wherein the growth is continued while replenishing a compound containing N from a source outside the reaction vessel.

Other References

  • "Preparation of GaN Single Crystals Using a Na Flux", H. Yamane et al., Chemical Mater, 1997, vol. 9, No. 2, pp. 413-416
  • "InGaN/GaN/AlGaN-Based Laser Diodes With Cleaved Facets Grown on GaN Substrates", S. Nakamura et al., Applied Physics Letters, 1998, vol. 73, No. 6, pp. 832-834
  • "Bulk and Homoepitaxial GaN-growth and Characterization", S. Porowski, Journal of Crystal Growth, 1998, vol. 189/190, pp. 153-158
  • "InGaN/GaN/AlGaN-Based Laser Diodes With Modulation-Doped Strained-Layer Superlattices", S. Nakamura et al., Japanese Journal of Applied Physics, 1997, vol. 36, No. 12A, pp. 1568-157
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