Patent References 3230044 Process for making beta-zinc diphosphide monocrystals (whiskers) Patent #: 4692203 InventorApplicationNo. 947863 filed on 09/21/1992US Classes:136/252, Cells136/265, Copper, lead, or zinc containing257/431, Light257/613, INCLUDING SEMICONDUCTOR MATERIAL OTHER THAN SILICON OR GALLIUM ARSENIDE (GAAS) (E.G., PB X SN 1-X TE)257/E31.026, Including, apart from doping material or other impurity, only compound other than Group II-VI, III-V, and IV compound (EPO)257/E31.126Transparent conductive layer (e.g., transparent conductive oxide (TCO), indium tin oxide (ITO) layer) (EPO)ExaminersPrimary: Weisstuch, AaronAttorney, Agent or FirmInternational ClassesH01L 031/06H01L 031/039.2 AbstractA thin film, photovoltaic, solar energy conversion device comprising: a thin-film, photovoltaic layer; a transparent electrical conducting layer in contact with said photovoltaic layer; a back electrical conducting layer in contact with said photovoltaic layer; fabricated on a suitable substrate; said photovoltaic layer being of a material selected from the class consisting of: monoclinic zinc diphosphide (also referred to as beta zinc diphosphide and indicated by ଲ-ZnP2); copper diphosphide (CuP2); magnesium tetraphosphide (MgP4); gamma-iron tetraphosphide (γ-FeP4) and mixed crystals formed from these four materials. A thin film fabrication process is presented that produces high efficiency, low-cost photovoltaic layers of the above-indicated class.Other References
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