Method and apparatus for producing carbon nanotubes
Patent 6413487 Issued on July 2, 2002. Estimated Expiration Date: June 2, 2020. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.
A method and apparatus for catalytic production of carbon nanotubes. Catalytic particles are exposed to different process conditions at successive stages wherein the catalytic particles do not come in contact with reactive (catalytic) gases until preferred process conditions have been attained, thereby controlling the quantity and form of carbon nanotubes produced. The method also contemplates methods and apparatus which recycle and reuse the gases and catalytic particulate materials, thereby maximizing cost efficiency, reducing wastes, reducing the need for additional raw materials, and producing the carbon nanotubes, especially SWNTs, in greater quantities and for lower costs.
Other References
Crystalline Ropes of Metallic Carbon Nanotubes, Thess et al., Science, vol. 273, pp. 483-487, Jul. 1996
Large-Scale Synthesis of Aligned Carbon Nanotubes, Li et al., Science, vol. 274, pp. 1701-1703, Dec. 1996
International Search Report, PCT/US00/15362. No Date
B. Kitiyanan et al., "Controlled production of single-wall carbon nanotubes by catalytic decomposition of CO on bimetallic Co-Mo catlaysts", Chemical Physics Letters, 317 (2000), pp. 497-503, Feb. 4, 2000
V. Brotons et al., "Catalytic influence of bimetallic phases for the synthesis of single-walled carbon nanotubes", Journal of Molecular Catalysis, A: Chemical 116 (1997) 397-403
I. Willems et al., "Control of the outer diameter of thin carbon nanotubes synthesized by catalytic decomposition of hydrocarbons", Chemical Physics Letters, 317 (2000) pp. 71-76
Che et al., "Chemical Vapor Deposition Based Synthesis of Carbon Nanotubes and Nanofibers Using a Template Method", Chemical Mater. 1998, 10, pp. 260-267. No Month
Chen et al., "Growth of carbon nanotubes by catalytic decompositon of CH4 or CO on a Ni-MgO catalyst", Carbon vol. 35, No. 10-11, pp. 1495-1501, 1997
Govindaraj et al., "Carbon structures obtained by the disproportionation of carbon monoxide over nickel catalysts", Materials Research Bulletin, vol. 33, No. 4, pp. 663-667, 1998
Hernadi et al., "Catalytic synthesis of carbon nanotubes using zeolite support", Elsevier Science Inc. 1996. No Month
Fonseca et al., "Synthesis of single-and multi-wall carbon nanotubes over supported catalysts", Applied Physics A, 67, pp. 11-22, 1998. No Month
Hafner et al., "Catalytic growth of single-wall carbon nanotubes from metal particles", Chemical Physics Letters, 296, pp. 195-202, Oct. 1998
Cassell et al., "Large Scale CVD Synthesis of Single-Walled Carbon Nanotubes", American Chemical Society, pp. 6483-6492, 1999
Krishnankutty et al.;"The Effect of Copper on the Structural Characteristics of Carbon Filaments Produced from Iron Catalyzed Decomposition of Ethylene," Catalysts Today, 37:295-307, 1997. No. Month
Iijima et al.; "Single-Shell Carbon Nanotubes of 1-nm Diameter", Nature 363:603-605, Jun. 1993
Bethune et al.; "Cobalt-Catalysed Growth of Carbon Nanotubes with Single-Atomic-Layer Walls," Nature, 363:605-607, Jun. 1993
Dai et al.; "Single-Wall Nanotubes Produced By Metal-Catalyzed Disproportionation of Carbon Monoxide," Chemical Physics Letters, 260:471-475, 1996
Ivanov et al.; "The Study of Carbon Nanotubes Produced by Catalytic Method," Chemical Physics Lettersm 223:329-335, Jun. 1994
Cheng et al.; "Large-Scale and Low-cost Synthesis of Single-Walled Carbon Nanotubes by the Catalytic Pyrolysis of Hydrocarbons," Applied Physics Letters, 72 (25) :3282-3284, Jun. 25, 1998
Cheng et al.;"Bulk Morphology and Diameter Distribution of Single-Walled Carbon Nanotubes Synthesized by Catalytic Decomposition of Hydrocarbons," Chemical Physics Letters, 289:602-610, 1998
Rinzler et al.; "Large-Scale Purification of Single-Wall Carbon Nanotubes: Process, Product, and Characterization," Applied Physics A, 67:29-37, 1998
Journet et al.; "Large-Scale Production of Single-Walled Carbon Nanotubes by the Electric-Arc Technique," Nature, 338:756-758, Aug. 1997
Yakobson et al.; "Fullerene Nanotubes: C1,000,000 and Beyond," American Scientist, 85:324-337, Jul.-Aug. 1997
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