U.S. patents available from 1976 to present.
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Surfactant process for promoting gas hydrate formation and application of the same

Patent 6389820 Issued on May 21, 2002. Estimated Expiration Date: Icon_subject February 10, 2020. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Gas hydrate cool storage system
Patent #: 4540501
Issued on: 09/10/1985
Inventor: Ternes ,   et al.

Gas hydrate storage system and method for using the gas hydrate storage system in automotive vehicles
Patent #: 5540190
Issued on: 07/30/1996
Inventor: Rogers, et al.

Surface active agents as gas hydrate inhibitors Patent #: 5841010
Issued on: 11/24/1998
Inventor: Rabeony, et al.

Inventors

Assignee

Application

No. 501766 filed on 02/10/2000

US Classes:

62/45.1STORAGE OF SOLIDIFIED OR LIQUIFIED GAS (E.G., CRYOGEN)

Examiners

Primary: Doerrler, William C.
Assistant: Drake, Malik N.

Attorney, Agent or Firm

International Class

F17C 003/00

Abstract

This invention relates to a method of storing gas using gas hydrates comprising forming gas hydrates in the presence of a water-surfactant solution that comprises water and surfactant. The addition of minor amounts of surfactant increases the gas hydrate formation rate, increases packing density of the solid hydrate mass and simplifies the formation-storage-decomposition process of gas hydrates. The minor amounts of surfactant also enhance the potential of gas hydrates for industrial storage applications.

Other References

  • Kalogerakis et al., SPE 25188; International Symposium on Oilfield Chemistry:"Effect of Surfactants on Hydrate Formation Kinetics"; New Orleans, LA, Mar. 2-5, 1993; pp. 375-383
  • A. D. MacKerell, Jr. J. Phys. Chem. 99: "Molecular Dynamics Simulation Analysis of a Sodium Dodecyl Sulfate Micelle in Aqueous Solution: Decreased Fluidity of the Micelle in Aqueous Solution: Decreased Fluidity of the Micelle Hydrocardon Interior"; 1995; pp. 1846-1855
  • H. Narita, T. Uchida, 2nd International Symposium on Gas Hydrates , Toulouse, France, "Studies on Formation/Dissociation Rates of Methane Hydrates"; pp. 191-197
  • A. Vysniauskas et al, Chemical Engineering Science 40;"Kinetics of Ethane Hydrate Formation"; 1985; pp. 299-303
  • E. Wanless, W. Ducker, J. Phys. Chem. 100; "Organization of Sodium Dodecyl Sulfate at the Graphite-Solution Interface"; 1996; pp. 3207-3214
  • G. Yevi et al; Journal of Energy Resources Technology 118; "Storage of Fuel in Hydrates for Natural Gas Vehicles (NGVs)"; 1996, pp. 209-213
  • Jeneil Biosurfactant Company--Product Sheet: "Biosurfactant-Rhamnolipids"; 1999; pp. 1-4
  • D. Herman et al.; Environmental Science & Technology, vol. 29, No. 9; "Removal of Cadmium, Lead, and Zinc From Soil by a Rhamnolipid Biosurfactant"; 1995; pp. 2280-2285
  • R.A. Goodnow et al.; Applied and Environmental Microbiology, vol. 56, No. 7, "Fate of Ice Nucleation-Active Pseudomonas syringae Strains in Alpine Soils and Waters and in Synthetic Snow Samples"; 1990; pp. 2223-2227
  • D.L. Glutnick; Biopolymers, vol. 26, "The Emulsan Polymer: Perspectives on a Microbial Capsule as an Industrial Product"; 1987; pp.S223-S240
  • T. Collett, 2nd International Symposium on Gas Hydrates, Toulouse, France, "Geologic Assessment of the Natural Gas Resources in the Onshore and Offshore Regions of the United States"; 1996; pp. 499-506
  • P. Englezos, 2nd International Symposium on Gas Hydrates, Toulouse, France, "Nucleation and Growth of Gas Hydrate Crystals in Relation to `Kinetic Inhibition`"; 1996; pp 147-153
  • J. Herri et al, 2nd International Symposium on Gas Hydrates, Toulouse, France, "Kinetics of Methane Hydrate Formation"; 1996; pp 243-250
  • Y. Mori et al, 2nd International Symposium on Gas Hydrates, Toulouse, France, "Modeling of Mass Transport Across a Hydrate Layer Intervening Between Liquid Water and "Guest" Fluid Phases"; 1996; pp 267-274
  • M. J. Rosen; "Surfactants and Interfacial Phenomena"; 1978; pp 83-122
  • J. D. Rouse et al, Environmental Science Technology 29, "Micellar Solubilization of Unsaturated Hydrocarbon Concentrations as Evaluated by Semiequilibrium Dialysis"; 1995; pp 2484-2489
  • S. Thangamani et al, Environmental Science Technology 28, "Effect of Anionic Biosurfactant on Hexadecane Partitioning in Multiphase Systems"; 1994; pp 1993-2000
  • E. D. Sloan, Jr., "Clathrate Hydrates of Natural Gas"; pp 24-110
  • A. Vysniauskas et al, Chemical Engineering Science 38;"A Kinetic Study of Methane Hydrate Formation"; 1983; pp. 1061-1972
  • R. E. Rogers, Contact DE-AC26-97FT33203, "Natural Gas Hydrates Storage Project"; 1999; pp 1-49
  • R. E. Rogers, Contact DE-AC26-97FT33203, "Natural Gas Hydrates Storage Project Phase II. Conceptual Design and Ecomomic Study"; 1999; pp 1-3
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