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Hard film, sliding member covered with hard film, and manufacturing method thereof

Patent 6372369 Issued on April 16, 2002. Estimated Expiration Date: Icon_subject September 13, 2020. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Nonferrous piston ring with hard surface treatment layer
Patent #: 5316321
Issued on: 05/31/1994
Inventor: Ishida, et al.

Hard coating material, sliding member coated with hard coating material and method for manufacturing sliding member
Patent #: 5449547
Issued on: 09/12/1995
Inventor: Miyazaki, et al.

Sliding contact-making structures in internal combustion engine
Patent #: 5549086
Issued on: 08/27/1996
Inventor: Ozawa, et al.

Piston ring
Patent #: 5743536
Issued on: 04/28/1998
Inventor: Komuro, et al.

Hard coating material, sliding member covered with hard coating material and manufacturing method thereof Patent #: 6060182
Issued on: 05/09/2000
Inventor: Tanaka, et al.

Inventors

Assignee

Application

No. 661410 filed on 09/13/2000

US Classes:

428/698, Carbide-, nitride-, or sulfide-containing layer106/286.1, Inorganic materials only containing at least one metal atom427/523, Ion plating or implantation428/3361 mil or less

Examiners

Primary: Turner, Archene

Attorney, Agent or Firm

International Classes

F16J 009/26
C23C 026/00

Foreign Application Priority Data

1999-09-24 JP

Abstract

A nitrided layer is formed on a piston ring and a hard film is formed by arc ion plating on the nitrided layer at the outer circumferential surface. The hard film has a crystal structure comprised of mixed phases of CrN and TiN, and contains oxygen in a solid solution state in the CrN and TiN crystals. The hard film comprises chromium of 40 to 75 percent by weight, titanium of 10 to 40 percent by weight, oxygen of 0.5 to 15 percent by weight, and the remainder of nitrogen. The crystal particle size is within 1 μm. The Vickers hardness of the hard film is in a range of 1300 to 2300. The crystals of CrN and TiN have a preferred orientation of (200) surface or preferred orientation of (111) surface parallel to a surface being covered, and has a columnar structure developing in a columnar shape from the base material toward the film surface. Carbon in a solid solution state may be contained instead of oxygen, and both oxygen and carbon may be contained in a solid solution state. An under film of CrN may be formed between the nitrided layer and the hard film.

Other References

  • English abstract of CN 1102693 published May 17, 1995.
  • English abstract of JP 03247766 published Nov. 5, 199
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