U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Method and compositions for spray molding polyurethane three dimensional objects

Patent 6362302 Issued on March 26, 2002. Estimated Expiration Date: Icon_subject November 29, 2019. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Articles coated with a cured composition of hydroxy(polyalkylenecarbonyloxy)alkyleneoxazolidine and a polyisocyanate
Patent #: 4032686
Issued on: 06/28/1977
Inventor: Emmons

Moisture curing polymers prepared from polyfunctional isocyanates and a dioxazabicyclo octane
Patent #: 4101527
Issued on: 07/18/1978
Inventor: Cunningham ,   et al.

Hydrocurable oxazolidine isocyanate prepolymer compositions
Patent #: 4118376
Issued on: 10/03/1978
Inventor: Pedain ,   et al.

Multilayered elastomeric printing plate
Patent #: 4264705
Issued on: 04/28/1981
Inventor: Allen

Ambient hydrocurable coating and adhesives compositions
Patent #: 4299867
Issued on: 11/10/1981
Inventor: Emmons ,   et al.

Process for the preparation of stable aqueous dispersions of oligourethanes or polyurethanes and their use as coating compounds for flexible or rigid substrates
Patent #: 4306998
Issued on: 12/22/1981
Inventor: Wenzel ,   et al.

Ambient hydrocurable coating compositions
Patent #: 4373008
Issued on: 02/08/1983
Inventor: Emmons ,   et al.

Hydrocurable ambient curing polyepoxide coating and adhesive compositions and method of using them
Patent #: 4376844
Issued on: 03/15/1983
Inventor: Emmons ,   et al.

Process for coating one pot moisture curable coating composition onto non-porous substrate and article
Patent #: 4396681
Issued on: 08/02/1983
Inventor: Rizk ,   et al.

Low-halogen-content, thermoplastic polyurethane elastomer having improved flame resistance by the addition of a 4-component additive combination, its production and its use
Patent #: 4397974
Issued on: 08/09/1983
Inventor: Goyert ,   et al.

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Inventor

Application

No. 449871 filed on 11/29/1999

US Classes:

528/73, Reactant contains at least one heterocyclic ring264/309, Spraying or flinging material against a shaping surface264/337, Utilizing particular mold material521/158, With ketone, aldehyde, or aldehyde derivative521/163, With nitrogen containing reactant524/789, Elemental silicon, soil, or inorganic silicon compound as DNRM528/76With ether or thioether compound containing at least two -C-X-C- groups

Examiners

Primary: Gorr, Rachel

Attorney, Agent or Firm

International Class

C08G 018/32

Abstract

A method of producing three dimensional polyurethane shapes by spray molding a quasi-gel like polymer precursor composition that is first mixed and then sprayed by a spray gun. The spray coating of quasi-gel polymer precursor composition subsequently cures to form a molded polyurethane polymer shape. Such artificial three dimensional shapes may include rocks, rock walls or faces, tree stumps or limbs, animals, architectural features or settings in which a certain visual appearance is desired. The method includes: creating a mold and supporting cradle having a mold cavity conforming to the exterior of shape desired, the mold having a substantial degree of flexibility; spraying a quasi-gel polymer precursor composition into the mold cavity, the quasi-gel polymer precursor composition comprising a mixture of an isocyanate portion and a curative portion and being mixed prior to introduction into a spray gun, carrying out the spraying to build up the molded three dimensional shape to a desired thickness and stripping the cradle and mold from the molded polyurethane three dimensional shape after the curing of the quasi-gel polymer precursor.

Other References

  • Klempner & Frisch; Polymeric Foams; 1991; pp. 80-8
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