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Synthesis of polycarbonates using Co2

Patent 6288202 Issued on September 11, 2001. Estimated Expiration Date: Icon_subject April 11, 2017. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3294772

3522228

3668139

3689462

3891605

Method for production of a high molecular weight polyester prepared from a prepolymer polyester having an optimal carboxyl content
Patent #: 4238593
Issued on: 12/09/1980
Inventor: Duh

Synthesis of polycarbonate from dialkyl carbonate and bisphenol diester
Patent #: 4452968
Issued on: 06/05/1984
Inventor: Bolon ,   et al.

Preparation of finely divided pulverulent crosslinked copolymers
Patent #: 4748220
Issued on: 05/31/1988
Inventor: Hartmann ,   et al.

Process for the preparation of linear aliphatic polycarbonate from cyclic aliphatic carbonate
Patent #: 4754017
Issued on: 06/28/1988
Inventor: Leitz ,   et al.

Method of treating hollow articles, in particular polyethylene terephthalate preforms
Patent #: 4764323
Issued on: 08/16/1988
Inventor: Al Ghatta

More ...

Inventors

Application

No. 827755 filed on 04/11/1997

US Classes:

528/196, With reactant having halo-C(=O)-halo, halo-C(=O)-O-, or -O-C(=O)-O- group528/198Polymerizing in the presence of a specified material other than a reactant and other than Group IA or Group IIA material as sole metal atom

Examiners

Primary: Mosley-Boykin, Terressa

Attorney, Agent or Firm

Foreign Patent References

  • 3537455A1 DE. 04/11/1987
  • 0 300 981 A1 EP. 01/11/1989
  • 0356815 EP 03/11/1990
  • 0356815 A3 EP 03/11/1990
  • 0 222 714 B1 EP. 03/11/1992
  • 0 269 583 B1 EP. 06/11/1993
  • 1172713 GB. 05/11/1967
  • 3177407 JP. 08/11/1991
  • WO 90/07536 WO. 07/11/1990
  • WO 96/39456 WO 12/11/1996

International Class

C08G 064/00

Abstract

A process of forming a polycarbonate comprises providing a reaction mixture of at least one polycarbonate-forming monomer and carbon dioxide; and then reacting the polycarbonate-forming monomer and carbon dioxide in the reaction mixture to form the polycarbonate. In one embodiment, the polycarbonate is present in a condensate, and the process further comprises removing carbon dioxide from the reaction mixture; and then collecting the condensate from the reaction mixture. Moreover, uncrystallized polycarbonate may be treated with carbon dioxide to form crystalline polycarbonate. The crystalline polycarbonate is then rendered useful for solid state polymerization.

Other References

  • E. Beckman et al.; Crystallization of Bisphenol a Polycarbonate Induced by Supercritical Carbon Dioxide, J. of Polymer Science: Part B: Polymer Physics 25:1511-1517 (1987)
  • Garg et al, "Thermodynamics of Polymer Melts Swollen With Supercritical Gases", Macromolecules, 1994, vol. 27, pp. 5643-5653
  • Condo et al., "Glass Transitions of Polymers with Compressed Fluid Diluents: Type II and III Behavior", Macromolecules, 1994, vol. 27, pp. 365-371
  • Iyer, V.S., et al., "Solid-State polymerization of Poly(aryl carbonate)s: A Facile Route to High Molecular Weight Polycarbonates", Macromolecules, 1993, vol. 26, pp. 1186-1187
  • Radhakrishnan, S., et al., "Structure and Morphology of Polycarbonate Synthesized by Solid State Polycondensation", Polymer, 1994, vol. 35, pp. 3789-3791
  • Beckman, et al., "Copolymerization of 1,2-Epoxycyclohexane and Carbon Dioxide Using Carbon Dioxide as Both Reactant and Solvent", Macromolecules, 1997, vol. 20, No. 3, pp. 368-372
  • Shuichi Oi, et al., "Direct synthesis of polycarbonates from CO2, diols, and dihalides", Macromolecular: Rapid Communications, Feb. 1994, vol. 15, No. 2, pp. 133-137
  • DeSimone et al., Dispersion Polymerizations In Supercritical Carbon Dioxide, Science, 265:356-359 (Jul. 15, 1994)
  • H. Mark et al., Polyesters, The Encyclopedia of Polymer Science and Engineering, Eds., 2d ed., 12:1-60 (1985)
  • M. McHugh et al., Supercritical Fluid Chromatography Analysis Of Polystyrene, Excerpts from Supercritical Fluid Extraction, EDS., pp. 147-159 (1986)
  • Shaffer et al., Chain Polymerizations In Inert Near- and Supercritical Fluids, TRIP 3, No. 5:146-153, (May 1995)
  • Varadarajan, Free Radical Polymerization In Supercritical Fluid Solvents, Doctoral Thesis Digest, pp. 2-34, Nov. 29, 1990
  • Scholsky, Supercritical Polymerication Reactions, pp. 685-686
  • V. Krukonis et al., Supercritical Fluid Chromatography Analysis of Polystyrene, Polymer Fractionation, pp. 146-147, 156-159, 244-245, 248-24
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