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Method for fabrication of patterned carbon nanotube films

Patent 6277318 Issued on August 21, 2001. Estimated Expiration Date: Icon_subject August 18, 2019. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Field emission cathode having an electrically conducting material shaped of a narrow rod or knife edge
Patent #: 5773921
Issued on: 06/30/1998
Inventor: Keesmann, et al.

Carbon fiber-based field emission devices Patent #: 5872422
Issued on: 02/16/1999
Inventor: Xu, et al.

Inventors

Application

No. 376457 filed on 08/18/1999

US Classes:

264/346, To anneal or temper264/235, Annealing264/236, Completing vulcanization or polymerization264/298, By casting on a liquid surface264/319, Applying heat or pressure264/345, By a temperature change264/446, Limited to treatment of surface or coated surface428/206Including particulate material

Examiners

Primary: Dixon, Merrick

Attorney, Agent or Firm

Foreign Patent References

  • WO 98 11588 WO. 03/13/1998

International Class

B29B 017/00

Abstract

A method for fabricating adherent, patterned carbon nanotube films is provided. According to the invention, a substrate is patterned with a carbide-forming material, a carbon-dissolving material, or a low melting point metal. Carbon nanotubes are then deposited onto the patterned substrate, but have relatively poor adhesion to either the substrate material or the patterned material. The substrate is then annealed, typically in vacuum, at a temperature dependent on the particular patterning material, e.g., a temperature at which carbide formation occurs, at which carbon dissolution occurs, or at which the low melting point metal melts. The annealing thereby provides an adherent nanotube film over the patterned areas, while the nanotubes deposited onto the non-patterned areas are easily removed, e.g., by blowing, rubbing, brushing and/or ultrasonication in a solvent such as methanol.

Other References

  • Fan, S. et al., "Self-Oriented Regular Arrays of Carbon Nanotubes and their Field Emission Properties", Science, vol. 283, p. 512 (1999)
  • Xu et al., "A Method for Fabricating Large-Area, Patterned, carbon Nanotube Field Emitters", Appl. Phys. Lett., vol. 74, p. 2549 (1999)
  • Iijima, S., Nature, vol. 354, p. 56 (1991)
  • Ebbesen, T. W. et al., Nature, vol. 358, p. 220 (1992)
  • Yakobson, B. I. American Scientists, vol. 85, p. 324 (1997)
  • Fan et al., Science, vol. 283, p. 512 (1999)
  • Xu et al., Appl. Phys. Lett., vol. 74, p. 2549 (1999)
  • Massalski, T. B. Binary Alloy Phase Diagrams, vol. I, ASM International
  • Shelimov, K. B. et al., "Purification of Single Wall Nanotubes by Ultrasonically Assisted Filtration", Chem. Phys. Lett., vol. 282, p. 429 (1998)
  • U.S. Patent application Serial No. 09/296572, filed on Apr. 22, 1999
  • U.S. Patent application Serial No. 09/351537, filed on Jul. 12, 199
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