U.S. patents available from 1976 to present.
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Solution mining of carbonate/bicarbonate deposits to produce soda ash

Patent 6251346 Issued on June 26, 2001. Estimated Expiration Date: Icon_subject August 20, 2017. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

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Inventors

Assignee

Application

No. 914990 filed on 08/20/1997

US Classes:

423/206.2, Alkali carbonate from trona23/302T, Sodium compounds299/4, Input and output wells299/5, Dissolving or chemical reaction423/421, Alkali metal containing (Li, Na, K, Rb, or Cs)423/422Hydrogen containing (bicarbonate)

Examiners

Primary: Straub, Gary P.

Attorney, Agent or Firm

Foreign Patent References

  • 15822 GB. 07/13/1892
  • 883202 GB. 11/13/1961
  • 1 495 530 GB. 12/13/1977
  • 2 098 973 GB. 12/13/1982

International Class

C01D 007/12

Abstract

A solution mining process for recovering sodium values from an underground deposit of a sodium bicarbonate containing ore is disclosed. The process involves contacting the ore with an aqueous sodium carbonate-containing solution to produce a dilute brine which is stripped with steam to reduce the bicarbonate content and increase the carbonate content. The dilute carbonate/bicarbonate solution from the stripper is fed to a sodium carbonate decahydrate crystallizer to produce pure sodium carbonate decahydrate crystals and a mother liquor containing less than about 4% sodium bicarbonate.

Other References

  • Butler, J.N., Carbon Dioxide Equilibria and Their Application, Lewis Publishers, Chelsea, MI, pp. 30-39, 221, 1991
  • Defensive Publication, United States Patent Office, "Process For Producing Crystalline Anhydrous Sodium Carbonate", T928,002, 1 page, Nov. 5, 1974
  • Eickmeyer, A.G., "Carbon Dioxide Removal, IV, Catacarb", Fertilizer Science Technology Series, pp. 165-169, 1974
  • Garrett, D., "Solution Mining", Natural Soda Ash, Von Nostrand Reinhold, New York, NY, 1992, pp. 336-355
  • Harned et al., "The Thermodynamics of Ionized Water in Sodium Chloride Solutions", vol. 57, pp. 1873-1876, Oct. 1935
  • Mahajani et al., "The Stripping of CO2 From Amine-Promoted Potash Solutions at 100° C", Chemical Engineering Science, vol. 38, No. 2, pp. 321-327, 1983
  • Nii et al., "Regeneration of CO2 -Loaded Carbonate Solution By Reducing Pressure", Journal of Chemical Engineering of Japan, vol. 28, No. 2, pp. 148-153, 1995
  • Peiper et al., "Thermodynamics of Aqueous Carbonate Solutions Including Mixtures of Sodium Carbonate, Bicarbonate and Chloride", J. Chem. Thermodynamics, 14, pp. 618-638, 1982
  • Pohorecki et al., "Desorption with chemical reaction in the system CO2 -aqueous solution of potassium carbonate", The Chemical Engineering Journal, 46, pp. 1-7, 1991
  • Rao, D. Phaneswara, "Design of packed towers for absorption and desorption of carbon dioxide using hot promoted K2 CO3 solution", Gas Separation& Purification, vol. 5, pp. 177-180, Sep. 1991
  • Sarbar et al., "The activity and osmotic coefficients of aqueous sodium bicarbonate solutions", Chem. Thermodynamics, 14, pp. 967-976, 1982
  • Savage et al., "Chemical Absorption and Desorption of Carbon Dioxide From Hot Carbonate Solutions", Chemical Engineering Science, vol. 35, pp. 1513-1522, 1980
  • Taylor, E., "Thermodynamics of Sodium Carbonate in Solution", Institute of Paper Chemistry, pp. 653-657, Jul. 1955
  • Vanderzee, Cecil, "Thermodynamic properties of solutions of a hydrolyzing electrolyte: relative partial molar enthalpies and heat capacities, solvent activities, osmotic coefficients, and solute activity coefficients of aqueous sodium carbonate", J. Chem. thermodynamics, 14, pp. 1051-1067, 1982
  • Yakovlev et al., "Constant of the Second Stage of Dissociation of Carbonic Acid in Concentrated Na2 SO4 Solutions", Zh. Prikl. Khim(Leningrad), vol. 62, No. 6, pp. 1276-1277, 1989
  • ZA 87-9599 871222 South African Patent (Abstract Only: Chemical Abstract No. 110:176149), No Dat
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