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US Patent 6228335 - Process for the production of sodium carbonate crystals

US Patent Issued on May 8, 2001
Estimated Patent Expiration Date: Icon_subject December 10, 2017Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.
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Abstract

A process for the production of soda ash by withdrawing an aqueous mining solution containing dissolved sodium carbonate and at least about 1 wt % sodium bicarbonate from an underground alkali source; stripping CO2 gas from the withdrawn aqueous mining solution, to convert sodium bicarbonate dissolved therein to sodium carbonate; co-crystallizing sodium carbonate monohydrate and sodium sesquicarbonate by evaporation of water from the CO2 -stripped aqueous mining solution, without co-crystallization of anhydrous sodium carbonate, to form a slurry of crystalline solids in an aqueous liquor; recovering crystalline solids from the slurry; and calcining the recovered crystalline solids to produce soda ash.

Inventors

Assignee

Application

No. 987978 filed on 12/10/1997

US Classes:

423/206.2, Alkali carbonate from trona423/421, Alkali metal containing (Li, Na, K, Rb, or Cs)423/426Densifying soda ash

Field of Search

423/206.2, Alkali carbonate from trona423/206.1, Mixture contains organic or carbonaceous impurity423/426, Densifying soda ash423/421, Alkali metal containing (Li, Na, K, Rb, or Cs)23/302T, Sodium compounds23/297, With extraction23/298, From natural sources299/4, Input and output wells299/5Dissolving or chemical reaction

Examiners

Primary: Bos, Steven

Attorney, Agent or Firm

US Patent References

2133455, 2267136, 2388009, 2625384, 3050290, 3113834, 3119655, 3184287, 3246962, 3264057, 3273958, 3273959, 3451767, 3953073, Process for the solution mining of subterranean sodium bicarbonate bearing ore bodies
Issued on: 04/27/1976
Inventor: Kube
4252781, Preparation of sodium carbonate anhydride
Issued on: 02/24/1981
Inventor: Fujita ,   et al.
4283372, Recovery of alkali values from sodium bicarbonate-containing ore with ammonia
Issued on: 08/11/1981
Inventor: Frint ,   et al.
4288419, Enhanced recovery of sodium carbonate from NaCl-containing sodium carbonate solutions
Issued on: 09/08/1981
Inventor: Copenhafer ,   et al.
4519806, Enhanced recovery of soda ash from aqueous sodium carbonate solutions containing Na2 SO4 - and NaCl
Issued on: 05/28/1985
Inventor: Copenhafer ,   et al.
4557910, Production of soda ash from nahcolite
Issued on: 12/10/1985
Inventor: Meadow
4652054, Solution mining of trona or nahcolite ore with electrodialytically-produced aqueous sodium hydroxide
Issued on: 03/24/1987
Inventor: Copenhafer ,   et al.
4654204, Production of sodium bicarbonate by reversion of soda-type feed salt
Issued on: 03/31/1987
Inventor: Copenhafer ,   et al.
4869882, Recovery of sodium carbonate values from contaminated dilute soda ash streams
Issued on: 09/26/1989
Inventor: Dome ,   et al.
5043149, Soda ash production
Issued on: 08/27/1991
Inventor: Frint, et al.
5262134, Process for producing sodium salts from brines of sodium ores
Issued on: 11/16/1993
Inventor: Frint, et al.
5283054, Process for producing sodium salts from brines of sodium ores
Issued on: 02/01/1994
Inventor: Copenhafer, et al.
5396863, Installation and process for the crystallization of an inorganic substance and process and installation for the crystallization of sodium carbonate monohydrate
Issued on: 03/14/1995
Inventor: Ninane, et al.
5609838, Equilibrium production of sodium carbonate from sodium bicarbonate
Issued on: 03/11/1997
Inventor: Neuman, et al.
5618504, Method for recovery of alkali values from trona using sequential crystallization
Issued on: 04/08/1997
Inventor: Delling, et al.
5766270Solution mining of carbonate/bicarbonate deposits to produce soda ash
Issued on: 06/16/1998
Inventor: Neuman, et al.

International Classes

C01D 007/00
C22B 026/00

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