U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Alkali metal electrochemical cell having an improved cathode activated with a nonaqueous electrolyte having a carbonate additive

Patent 6221534 Issued on April 24, 2001. Estimated Expiration Date: Icon_subject November 25, 2018. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

2583589

3489611

3567515

3825445

Electrochemical cells with non-aqueous electrolytes containing macroheterocyclic compounds
Patent #: 4132837
Issued on: 01/02/1979
Inventor: Soffer

Cells having cathodes containing Cs S cathode-active materials
Patent #: 4143214
Issued on: 03/06/1979
Inventor: Chang ,   et al.

Non-aqueous primary cell
Patent #: 4224389
Issued on: 09/23/1980
Inventor: Peled

Additive for electrochemical cell stability
Patent #: 4264689
Issued on: 04/28/1981
Inventor: Moses

Activating carbonaceous electrodes
Patent #: 4273839
Issued on: 06/16/1981
Inventor: Carr ,   et al.

Metal oxide composite cathode material for high energy density batteries
Patent #: 4310609
Issued on: 01/12/1982
Inventor: Liang ,   et al.

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Inventors

Assignee

Application

No. 200304 filed on 11/25/1998

US Classes:

429/347, Organic solute component in aqueous electrolyte429/219, Silver component is active material429/220, Copper component is active material429/231.2, Alkalated vanadium (V) chalcogenide429/231.5Vanadium (V), chromium (Cr), niobium (Nb), molybdenum (Mo), titanium (Ti), or tungsten (W) component is active material

Examiners

Primary: Weiner, Laura

Attorney, Agent or Firm

Foreign Patent References

  • WO 96/29750 WO. 09/25/1996

International Class

H01M 006/04

Abstract

The present invention is directed to an unexpected benefit in a lithium cell derived from using a combination of silver vanadium oxide prepared in a temperature range of about 450° C. to about 500° C. activated with a nonaqueous electrolyte having a passivation inhibitor additive selected from a nitrite, a nitrate, a carbonate, a dicarbonate, a phosphonate, a phosphate, a sulfate and hydrogen fluoride, and mixtures thereof. The benefits include additional battery life resulting from a reduction in voltage delay and RDC build-up. A preferred electrolyte is 1M LiAsF6 in a 50:50 mixture, by volume, of PC and DME having dibenzyl carbonate added therein.

Other References

  • R.A. Leising and E.S. Takeuchi, Chemistry of Materials, 5,738-742 (1993
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