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Process for producing single wall nanotubes using unsupported metal catalysts

Patent 6221330 Issued on April 24, 2001. Estimated Expiration Date: Icon_subject August 4, 2017. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Process for preparing fine carbon fibers in a gaseous phase reaction
Patent #: 4572813
Issued on: 02/25/1986
Inventor: Arakawa

Process for preparing carbon fibers in gas phase growth
Patent #: 4876078
Issued on: 10/24/1989
Inventor: Arakawa, et al.

Process for producing graphite whiskers
Patent #: 5039504
Issued on: 08/13/1991
Inventor: Kageyama, et al.

Method for forming carbon fibers
Patent #: 5374415
Issued on: 12/20/1994
Inventor: Alig, et al.

Carbon fibers and method for their production Patent #: 5424054
Issued on: 06/13/1995
Inventor: Bethune, et al.

Inventors

Assignee

Application

No. 910495 filed on 08/04/1997

US Classes:

423/447.3, From gaseous reactants423/445B, Fullerene (e.g., C60, C70, etc.)423/447.2Product

Examiners

Primary: Griffin, Steven P.
Assistant: DiMauro, Peter

Attorney, Agent or Firm

Foreign Patent References

  • 2248230 GB 01/13/1992
  • 6-322615 JP. 11/13/1994
  • 9-188509 JP. 07/13/1997

International Classes

D01F 009/12
D01F 009/127

Abstract

A process for producing hollow, single-walled carbon nanotubes by catalytic decomposition of one or more gaseous carbon compounds by first forming a gas phase mixture carbon feed stock gas comprising one or more gaseous carbon compounds, each having one to six carbon atoms and only H, O, N, S or Cl as hetero atoms, optionally admixed with hydrogen, and a gas phase metal containing compound which is unstable under reaction conditions for said decomposition, and which forms a metal containing catalyst which acts as a decomposition catalyst under reaction conditions; and then conducting said decomposition reaction under decomposition reaction conditions, thereby producing said nanotubes.

Other References

  • Dai, et al., "Single-Wall Nanotubes Produced by Metal-Catalyzed Disproportionation of Carbon Monoxide", Chemical Physics Letters, vol. 260, pp. 471-475 (Jul., 1996)
  • Terrones, et al., "Controlled Production of Aligned-Nanotube Bundles", Nature, pp. 52-55, (Jul., 1997)
  • Thess et al., "Crystalline Ropes of Metallic Carbon Nanotubes", Science, vol. 273, pp. 483-487, (Jul. 26, 1996)
  • Guo et al., "Catalytic Growth of Single-Walled Nanotubes by Laser Vaporization", Chemical Physical Letter, pp. 49-55 (1995), no month
  • Qin, L.C. "CVD Synthesis of Carbon Nanotubes", J. Materials Science Letters, vol. 16, #6, pp. 457-459, Mar. 1997.
  • Sen, R. et al. "Carbon Nanotubes by the Metallocene Route", Chem. Phys Lett., vol. 267, pp. 276-280, Mar. 1997.
  • Kiang, C-H., et al. "Carbon Nanotubes with Single-Layer Walls", Carbon, vol. 33, pp 903-914, 1995.
  • Endo, et al., "Grow Carbon Fibers in the Vapor Phase", Chemtech, pp. 568-576 (Sep. 1, 1988)
  • Endo et al., "The Production and Structure of Pyroltic Carbon nanotubes (PCNTs)," J. Phys. Chem. Solids, vol. 54, No. 12, pp. 1841-1848 (1993)
  • Ebbesen et al., "Large-Scale synthesis of carbon nanotubes", Nature, vol. 358, pp. 220-222 (Jul.16, 1992)
  • Iijima, et al. "Pentagons, heptagons and negative curvature in graphite microtubule growth", Nature, vol. 356, pp. 776-778 (1992)
  • Sumio Iijima, "Helucal microtubules of graphitic carbon", Nature, vol. 354, No. 6348, pp. 56-58(Nov. 7, 1991
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