U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Barrier discharge conversion of Hg, SO2 and NOx

Patent 6117403 Issued on September 12, 2000. Estimated Expiration Date: Icon_subject December 29, 2018. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3745751

3856476

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Removal of nitric oxide from waste gases and recovery as nitric acid
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Process and apparatus for electrostatic purification of dust- and pollutant-containing exhaust gases in multiple-field precipitators
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NOx reduction by sulfur tolerant coronal-catalytic apparatus and method
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Inventors

Assignee

Application

No. 214358 filed on 12/29/1998

US Classes:

423/210, MODIFYING OR REMOVING COMPONENT OF NORMALLY GASEOUS MIXTURE95/59, Electrode treating (e.g., coating, cleaning, etc.)95/65, Liquid addition precedes electrical precipitation95/75, By liquid flushing96/53, Liquid spray means96/77, Serially arranged ionizing and collecting or agglomerating fields96/79, Collecting electrodes are flat plates96/86, Parallel disk or plate collector unit204/157.3, Removing a component from normally gaseous mixture204/157.46, Nitrogen containing product produced204/157.49, Sulfur containing product produced204/174, Sulfur-oxygen compounds204/177, Nitrogen compounds422/169, Including means providing sequential purification stages422/172, And means downstream of a stage for injecting a reactant into waste gas for interreaction in subsequent stage422/174, Electrical type423/215.5, Solid component423/235, Nitrogen or nitrogenous component423/242.1Sulfur or sulfur containing component

Examiners

Primary: Tran, Hien

Attorney, Agent or Firm

International Classes

B03C 003/00
B03C 003/16

Abstract

A process and apparatus for reducing particulate, nitrogen oxides ("NOx"), sulfur dioxide ("SO2 "), and mercury ("Hg") emissions from the combustion exhaust of fossil fuel fired plants while producing an end product that is commercially useful, comprising the steps of oxidizing Hg, NOx and SO2 using a barrier, pulse, corona, or electron beam electrical discharge apparatus (100) to produce HgO and the acids HNO3 and H2 SO4 collecting the HgO, acids and particulates in a wet ESP (120), and separating the particulates from the collected acid mixture, then separating and concentrating the acids for industrial use.

Other References

  • McLarnon, Christopher R., Nitrogen Oxide Decomposition by Barrier Discharge, Dissertation for Doctor of Philosophy Degree in Chemical Engineering, University of New Hampshire, May 1996
  • Penetrante, Bernie M., Effect of Electrical Parameters on the Chemical Kinetics of Plasma-Based Air Pollution Control, Applications of Electrostatics for Control of Gas Phase Air Pollutants Workshop, Cincinnati, Ohio, Aug. 22, 1997
  • Helfritch, Dennis J., Plasma Technologies Applied to Air Pollution Control, Applications of Electrostatics for Gas Phase Air Pollutants Workshop, Cincinnati, Ohio, Aug. 22, 1997
  • Monroe, Larry S., et al., Testing of a Combined Dry and Wet Electrostatic Precipitator for Control of Fine Particulate Emissions from a Coal-Fired Boiler, EPRI-DOE-EPA Combined Utility Air Pollutant Control Symposium, Washington, DC, Aug. 25-29, 1997
  • Masuda, S. et al., "Pulse Corona Induced Plasma Chemical Process . . . ," Proceedings 3rd International Conference on Electrostatic Precipitation, Padova, Italy, pp. 667-676, Oct. 1987
  • Urabe, T. et al. "Experimental Studies on Mercury Vapor Removal by Corona Discharge . . . ", Chemical Abstracts, vol. 109, #236097, Oct. 1987
  • Dhali, S.K., et al. "Dielectric Barrier Discharge for Processing of SO2/NOx", Journal of Applied Physics, vol. 69, pp 6319-6324, May 199
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