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Olefin epoxidation catalysts

Patent 6114551 Issued on September 5, 2000. Estimated Expiration Date: Icon_subject October 4, 2019. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Elastic bushing having fluid chamber filled with highly viscous fluid
Patent #: 4883260
Issued on: 11/28/1989
Inventor: Kanda

Epoxidation process and catalyst therefore
Patent #: 5374747
Issued on: 12/20/1994
Inventor: Saxton, et al.

Epoxidation process Patent #: 5621122
Issued on: 04/15/1997
Inventor: Saxton, et al.

Inventors

Assignee

Application

No. 412773 filed on 10/04/1999

US Classes:

549/510, The hetero ring is four-membered502/60ZEOLITE OR CLAY, INCLUDING GALLIUM ANALOGS

Examiners

Primary: Owens, Amelia

International Class

C07D 305/00

Abstract

A method of synthesizing an olefin epoxidation catalyst comprises the step of treating a porous crystalline aluminosilicate material having an X-ray diffraction pattern including d-spacing maxima at 12.4&#b1;0.25, 6.9&#b1;0.15, 3.57&#b1;0.07 and 3.42&#b1;0.07 Angstrom, such as MCM-22, with a dealuminating agent under conditions effective to remove framework aluminium from the material and produce a dealuminated product. The dealuminated product is then treated with a titanium-containing material under conditions effective to insert titanium into the dealuminated product and produce a titanium-containing, dealuminated catalyst composition.The resultant catalyst is useful in the epoxidation of olefins, such as propylene and cyclohexene, with hydrogen peroxide and organic hydroperoxides.

Other References

  • X.Gao, I.E. Wachs, "Titania-Silica as Catalyst: Molecular Structural Characteristics and Physico-Chemical Properties," Catal. Today, 1999, 51, 233-25
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