U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Paper sizing agents and methods

Patent 6114417 Issued on September 5, 2000. Estimated Expiration Date: Icon_subject October 16, 2018. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3061471

3061472

Anionic sizes
Patent #: 4001193
Issued on: 01/04/1977
Inventor: VON Bonin ,   et al.

Surface sizing of paper with an acrylic copolymer where scum formation is minimized
Patent #: 4030970
Issued on: 06/21/1977
Inventor: Tominaga ,   et al.

Surface sizing compositions for paper
Patent #: 4115331
Issued on: 09/19/1978
Inventor: Tominaga ,   et al.

Method of making aqueous emulsions of acrylate copolymers in the presence of a degraded starch protective colloid
Patent #: 4171407
Issued on: 10/16/1979
Inventor: Elser ,   et al.

Cationic sizing agent for paper and a process for the preparation thereof
Patent #: 4434269
Issued on: 02/28/1984
Inventor: Probst ,   et al.

Aqueous polymer dispersions preparation
Patent #: 4560724
Issued on: 12/24/1985
Inventor: Brabetz ,   et al.

Cationic sizing agent for paper, and a process for its preparation
Patent #: 4659431
Issued on: 04/21/1987
Inventor: Probst ,   et al.

Preparation of stable aqueous polymer dispersions which contain an alkenyl-aromatic compound as copolymerized units
Patent #: 4661557
Issued on: 04/28/1987
Inventor: Bubam ,   et al.

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Inventors

Assignee

Application

No. 174076 filed on 10/16/1998

US Classes:

524/27, Carbohydrate or derivative DNRM162/164.1, Synthetic resin162/164.6, Nitrogen containing162/168.1, Polymerized unsaturated compound162/175, Carbohydrate162/176, Cellulose (non-fibrous)162/177, Cellulose derivative (e.g., cellulose ester)162/180, Natural resin524/28, Algin or derivative524/35, Cellulose524/47, Starch or derivative or farinaceous meal or flour524/458, Polymerizing in the presence of water and in the presence of a solid polymer derived from ethylenic reactants only524/459, Solid polymer utilized contains vinyl alcohol units524/732, Carbohydrate or derivative as DNRM524/734Starch or derivative, farinaceous flour or meal

Examiners

Primary: Nutter, Nathan M.

Attorney, Agent or Firm

Foreign Patent References

  • 0173 300 A1 EP. 03/12/1986
  • WO 94/05855 WO. 03/12/1994
  • WO 96/34699 WO. 11/12/1996
  • WO 97/37078 WO. 10/12/1997
  • WO 99/09251 WO. 02/12/1999

International Classes

C08L 005/00
C08F 002/16

Abstract

Sizing agents comprised of dispersed synthetic polymers in an aqueous solution are provided, as well as methods for making these sizing agents and methods for using these sizing agents to size paper. Improved sizing is obtained by including recurring units of methyl acrylate, ethyl acrylate and/or propyl acrylate in the synthetic polymers.

Other References

  • T. Aslamazova, Colloids and Surfaces A:Physico chemical and Engineering Aspects 104(1995) 147-155, "Polymer-monomer and polymer-interactions and their effect on the stability of emulsifier-free acrylate latexes"
  • Zushun Zu, Polymer International 44(1997) 149-155, "Styrene-butyl Acrylate-N,N-Dimethyl-N-butyl-N-Methacrylamiedino Propyl Ammonium Bromide Emulsifier-free Emulsion Copolymerization"
  • Yi-Guan Tsai, "An Alternative Chemistry for Paper; Surface Size with High Performance and A Large Window of Operation," 1995 Papermakers Conference TAPPI Proceedings, pp. 427-434
  • M. Watson, "The Surface Treatment of Fine Business Papers," Ed J. Bronder, Surface Application of Paper Chemicals, Blackie, London (1997), pp. 192-207
  • T. R. Aslamazova, "Influence of Functional Comonomers on the Stability of Emulsifier-Free Acrylate Latexes," 1995, Colloid Journal, vol. 57, No. 2, 1995
  • T. R. Aslamazova, "Role of Polymer-Polymer-Monomer Interactions in the Stabilization of Emulsifier-Free Latexes," 1995, Colloid Journal, vol. 57, No. 2 1995, pp. 135-14
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