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Method of passivating copper interconnects in a semiconductor

Patent 6071808 Issued on June 6, 2000. Estimated Expiration Date: Icon_subject June 23, 2019. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

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Inventors

Application

No. 339085 filed on 06/23/1999

US Classes:

438/633, Simultaneously by chemical and mechanical means257/E21.3, Post treatment (EPO)257/E21.304, By chemical mechanical polishing (CMP) (EPO)257/E21.584, Barrier, adhesion or liner layer (EPO)438/624, Separating insulating layer is laminate or composite of plural insulating materials438/672, Plug formation (i.e., in viahole)438/687Copper of copper alloy conductor

Examiners

Primary: Smith, Matthew
Assistant: Rocchegiani, Renzo N.

Attorney, Agent or Firm

International Class

H01L 021/476.3

Abstract

A method of passivating copper interconnects is disclosed. A freshly electrodeposited copper interconnect such as formed as via/trench structures in semiconductor manufacturing is chemically converted to passivating surface of copper tungstate or copper chromate either through MOCVD reaction with vapors of tungsten or chromium alkoxides, or by pyrolytic reaction with tungsten or chromium carbonyl in the presence of O2. The copper interconnect having the formed passivation service is then chemically mechanically polished. The process can be used with various manufacturing processes, including single and dual damascene processes.

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