Gas hydrate regassification method and apparatus using steam or other heated gas or liquid
Patent 6028235 Issued on February 22, 2000. Estimated Expiration Date: October 14, 2017. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.
585/15, HYDRATE OR PRODUCTION THEREOF62/45.1, STORAGE OF SOLIDIFIED OR LIQUIFIED GAS (E.G., CRYOGEN)62/54.2, Controlled conversion of solidified gas to another phase62/54.3, Storing solidified gas585/800, PURIFICATION, SEPARATION, OR RECOVERY585/801By conversion of solid to gas, e.g., sublimation, etc., or by melting or squeezing out liquid from solid natural source
A method and apparatus for safely, conveniently, and inexpensively liberating gas from gas hydrates includes the use of a device, provided adjacent to or in the bulk gas hydrates, for exposing the gas hydrates to heat from a gas or liquid (preferably steam). The gas hydrates can be directly exposed to the gas or liquid or indirectly exposed through a thermally conductive coil or channel. The heat from the gas or liquid dissociates the gas hydrates into the corresponding gas component and water component. After liberation, the gas component can be collected for further storage, transport, or use. The apparatus further includes a mechanism for moving at least a portion of the gas or liquid through the device for exposing the gas hydrates to heat. The device for exposing the gas hydrates to heat also can be movable, so it can be maintained in close proximity to or in contact with the gas hydrates for continued efficient gasification of the hydrates.
Other References
W.P. Gee, et al., "The Solvent Dewaxing Process," Refiner & Natural Gasoline Manufacturer, vol. 15, No. 6 (1936), pp. 205-209-Jun., 1936
B. Miller, et al., "Hydrate Storage of Natural Gas," American Gas Association Monthly, vol. 28, No. 2 (1946), pp. 63-67, 92 Feb. 1946
D. Katz, et al., Handbook of Natural Gas Engineering, McGraw-Hill, New York (1959) pp. 189-221-no month
H.C. Kim, "Kinetics of Methane Hydrate Decomposition," Chemical Engineering Science, vol. 42, No. 7 (1987), pp. 1645-1653-no month
A.A. Trofimuk, et al., "The Dynamics of the Zone of Hydrate Formation and its Effect on the Temperature Regime of the Cryolithozone," Soviet Geology and Geophysics, vol. 27, No. 11 (1987), pp. 1-7-no month
I. Ridley, et al., "Gas Hydrates Keep Energy on Ice," New Scientist, No. 1601 (1988), pp. 53-58-Feb. 1988
Y.P. Handa, "A Calorimetric Study of Naturally Occuring Gas Hydrates," Industrial & Engineering Chemistry Research, vol. 27, No. 5 (1988), pp. 872-874-May 1988
L.F. Smirnov, "New Technologies Using Gas Hydrates," Theoretical Foundations of Chemical Engineering, vol. 23, No. 6 (1990), pp. 514-526 (Russian language original published at Teor. Osn. Khim. Tekhnol. V23(6), 808-822 (1989))-no month
E.D. Ershov, et al., "Experimental Investigations of the Microstructure of Agglomerate of Ice and Methane Hydrate," Soviet Engineering Geology, vol. 3 (1990), pp. 32-37-no month
E.D. Sloan, Gas Research Institute, Topical Report "The State-of-the-Art of Hydrates as Related to the Natural Gas Industry," GRI-91/0302, 1992 Jun. 1992
E.D. Ershov, et al., Experimental Research on Gas Hydrate Decomposition in Frozen Rocks, Cold Regions Science and Technology, vol. 20 (1992), pp. 147-156-no month
P. Englezos, "Clathrate Hydrates," Industrial & Engineering Chemical Research, vol. 32 (1993), pp. 1251-1274-no month
J.S. Gudmundsson, "Storing Natural Gas as Frozen Hydrate," SPE Production & Facilities, vol. 9, No. 1 (1994), pp. 69-73-Feb. 1994
R.D. Malone, "Gas Hydrate Geology and Geography," International Conference on Natural Gas Hydrates, Annals of the New York Academy of Sciences, vol. 715, pp. 225-231 1994-no month
K.A. Kvenvolden, "Natural Gas Hydrate Occurrence and Issues," International Conference on Natural Gas Hydrates, Annals of New York Academy of Sciences, vol. 715, pp. 232-246-1994 no month
J.S. Gudmundsson, et al., "Transport of Natural Gas as Frozen Hydrate," Proceedings of the Fifth International Offshore and Polar Engineering Conference, vol. I, The Hague, Netherlands, Jun. 1995, pp. 282-288
"Natural Gas Transport as Hydrates 25% Below Cost of LNG," Offshore, Nov. 1995, p. 26
J. Long, "Gas Hydrate Formation Mechanism and Kinetic Inhibition," Ph.D. Dissertation, 1994, Colorado School of Mines, Golden, Colorado-Apr. 1994
MS Peters et al., "Plant Design and Economics for Chemical Engineers", McGraw Hill, 1976, pp. 575-586-no mont