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Method for forming high dielectric constant metal oxides

Patent 6020024 Issued on February 1, 2000. Estimated Expiration Date: Icon_subject August 4, 2017. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Process for depositing an oxide epitaxially onto a silicon substrate and structures prepared with the process
Patent #: 5225031
Issued on: 07/06/1993
Inventor: McKee, et al.

Multi-LOCOS (local oxidation of silicon) isolation process
Patent #: 5374586
Issued on: 12/20/1994
Inventor: Huang, et al.

Process for growing a film epitaxially upon an oxide surface and structures formed with the process
Patent #: 5450812
Issued on: 09/19/1995
Inventor: McKee, et al.

Method of fabricating an isolation region for semiconductor device
Patent #: 5804492
Issued on: 09/08/1998
Inventor: Shen

Method of making deep sub-micron meter MOSFET with a high permitivity gate dielectric Patent #: 5834353
Issued on: 11/10/1998
Inventor: Wu

Inventors

Assignee

Application

No. 905755 filed on 08/04/1997

US Classes:

427/248.1, COATING BY VAPOR, GAS, OR SMOKE257/E21.193, On single crystalline silicon (EPO)257/E21.435, Lateral single gate single channel silicon transistor with both lightly doped source and drain extensions and source and drain self-aligned to sides of gate, e.g., LDD MOSFET, DDD MOSFET (EPO)257/E29.16, Gate conductor material being compound or alloy material (e.g., organic material, TiN, MoSi 2 ) (EPO)257/E29.165, Multiple layers (EPO)427/255.7, Plural coatings applied by vapor, gas, or smoke427/309, Inorganic base427/527, Silicon present in substrate, plating, or implanted layer438/287Gate insulator structure constructed of diverse dielectrics (e.g., MNOS, etc.) or of nonsilicon compound

Examiners

Primary: King, Roy V.

Attorney, Agent or Firm

Foreign Patent References

  • 0690487 A1 EP 01/13/1996

International Classes

C23C 016/00
H01L 021/336

Abstract

A method for forming a metal gate (20) structure begins by providing a semiconductor substrate (12). The semiconductor substrate (12) is cleaned to reduce trap sites. A nitrided layer (14) having a thickness of less than approximately 20 Angstroms is formed over the substrate (12). This nitrided layer prevents the formation of an oxide at the substrate interface and has a dielectric constant greater than 3.9. After the formation of the nitrided layer(14), a metal oxide layer (16) having a permittivity value of greater than roughly 8.0 is formed over the nitrided layer (14). A metal gate (20) is formed over the nitrided layer whereby the remaining composite gate dielectric (14 and 16) has a larger physical thickness but a high-performance equivalent oxide thickness (EOT).

Other References

  • Momiyama, et al., "Ultra-Thin Ta2O5/Si02 Gate Insulator with TiN Gate Technology for 0.1 μm MOSFET's", Symposium on VLSI Technology Digest of Technical Papers; pp. 135-136 (1997)
  • Kawkubo, et al., "Novel Ferroelectric Epitaxial (Ba,Sr) Ti03 Capacitor for Deep Sub-Micron Memory Applications", IEDM, pp. 695-698 (1996)
  • Lyu, et al., "Metal-Ferroelectric-Semiconductor Field-Effect Transistor (MFSFET) for Single Transistor Memory by Using Poly-Si Source/Frain and BaMgF4 Dielectric", IEDM, pp. 503-506 (1996)
  • Kwon, et al., "Ta2O5 Capacitors for 1 Gbit DRAM and Beyond", IEDM, pp. 835-838 (1994)
  • Kamiyama, et al. "Characterization of Ultra-Thin Capacitors Fabricated Using RTN Treatment Prior to CVD Ta2O5 Film Formation", Extended Abstracts of the 1992 International Conf on Solid State Devices and Materials, Tsukuba, pp. 521-526 (1992)
  • Nakata, et al., "W-Gate MOSFETs with Ta2O5/SiO2 Gate Insulator", Extended Abstracts of the 21st Conference on Solid State Devices and Materials, pp. 545-555 (1989
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