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Metal containing e-coat catalysts optionally with tin catalysts

Patent 6001900 Issued on December 14, 1999. Estimated Expiration Date: Icon_subject June 13, 2017. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Paint composition for cathodic electrodeposition
Patent #: 4256621
Issued on: 03/17/1981
Inventor: Shimokai ,   et al.

Catalyst composition and curable polymer compositions containing same
Patent #: 4395528
Issued on: 07/26/1983
Inventor: Leiner ,   et al.

Non-autocrosslinking binder combination for water-dilutable lacquers
Patent #: 4865704
Issued on: 09/12/1989
Inventor: Saatweber ,   et al.

Electrocoating composition containing blocked isocyanate, dialkyltin aromatic carboxylate and a bismuth or zirconium compound
Patent #: 5330839
Issued on: 07/19/1994
Inventor: Yasuoka, et al.

Electrodepositable compositions containing triorganotin catalysts Patent #: 5356529
Issued on: 10/18/1994
Inventor: Eswarakrishnan, et al.

Inventors

Assignee

Application

No. 874630 filed on 06/13/1997

US Classes:

523/410, Polymer derived from ethylenic reactant only derived from reactant containing oxygen heterocycle204/506, Bath contains separate crosslinking or curing agent502/102, Plural component system comprising A - Group I to IV metal hydride or organometallic compound - and B - Group IV to VIII metal, lanthanide or actinde compound - (i.e., alkali metal, Ag, Au, Cu, alkaline earth metal, Be, Mg, Zn, Cd, Hg, Sc, Y, Al, Ga, In, Tl, Ti, Zn, Hf, Ge, Sn or Pb hydride or organometallic compound and Ti, Zr, Hf, Ge, Sn, Pb, V, Nb, Ta, As, Sb, Bi, Cr, Mo, W, Po, Mn, Tc, Re, Iron group, Platinum group, atomic number 57 to 71 inclusive or atomic number 89 or higher compound)528/28Organic Si-free reactant is a nitrogen-containing compound

Examiners

Primary: Dawson, Robert A.
Assistant: Aylward, D.

Attorney, Agent or Firm

International Classes

C08K 003/20
C08L 063/02

Abstract

The invention comprises a curable composition comprising: (i) a blocked reactive component wherein the blocked reactive component is a blocked isocyanate or a blocked isothiocyanate; (ii) a functional compound reactive with the blocked reactive component, the functional compound containing reactive hydrogen; (iii) a catalyst for promoting the reaction of the reactive component with the blocked functional compound, wherein said catalyst is based on the reaction product of manganese, cobalt, nickel, copper, zinc, germanium, antimony, or bismuth, or the oxides thereof with a mercaptan, or an organic acid, wherein said organic acid is hexanoic, oxalic, adipic, lactic, tartaric, salicylic, thioglycolic, succinic, or mercapto succinic acid, or the reaction product of copper or germanium, or the oxides thereof with a lower aliphatic acid. The manganese, cobalt, nickel, copper, zinc, germanium, antimony, or bismuth catalysts can be used in conjunction with other compounds to promote the reaction, especially compounds based on tin, preferably organotin compounds. Water soluble catalysts are preferred. The coating composition can be electrocoated on a conductive substrate and cured.

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