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Method for predetermining a polymer for inhibiting hydrate formation

Patent 5900516 Issued on May 4, 1999. Estimated Expiration Date: Icon_subject October 10, 2017. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Method for controlling clathrate hydrates in fluid systems
Patent #: 5420370
Issued on: 05/30/1995
Inventor: Sloan, Jr.

Method for controlling clathrate hydrates in fluid systems
Patent #: 5432292
Issued on: 07/11/1995
Inventor: Sloan, Jr.

Method for inhibiting hydrate formation
Patent #: 5491269
Issued on: 02/13/1996
Inventor: Colle, et al.

Additives and method for controlling clathrate hydrates in fluid systems Patent #: 5639925
Issued on: 06/17/1997
Inventor: Sloan, Jr., et al.

Inventors

Application

No. 948504 filed on 10/10/1997

US Classes:

585/15, HYDRATE OR PRODUCTION THEREOF137/3, Mixing of plural fluids of diverse characteristics or conditions137/13, Affecting flow by the addition of material or energy166/310, Entraining or incorporating treating material in flowing earth fluid166/371, Including non-expulsive material placed in well208/48AA, Antifoulant additive507/90, PREVENTING CONTAMINANT DEPOSITS IN PETROLEUM OIL CONDUITS585/950Prevention or removal of corrosion or solid deposits

Examiners

Primary: Wood, Elizabeth D.

Attorney, Agent or Firm

International Classes

C07C 007/20
F17D 001/05

Abstract

A method for inhibiting the formation and/or agglomeration of clathrate hydrates in a petroleum fluid stream containing water is disclosed. The disclosed method uses predetermined inhibitors having a guest group, a polymer backbone, and an anchor group positioned between the guest group and the polymer backbone. The inhibitor predetermination method comprises selection of the polymer backbone, anchor group and guest group using several types of criteria. The polymer backbone should produce a substantially water soluble polymer in combination with the anchor group and the guest group. The anchor group should be a hydrophilic moiety with between one and four hydrogen bonding atoms. The guest group should be either a hydrophobic or amphiphilic moiety with a carbon atom to heteroatom ratio greater than or equal to about two to one and an average van der Waals diameter between about 3.8 angstroms and about 8.6 angstroms. Some inhibitors selected using the disclosed predetermination method have produced a subcooling temperature of about 30.0° F. Of 56 predetermined inhibitors, 18 have produced a subcooling temperature ࣙ24.0° F., 22 have produced a subcooling temperature <24.0° F. but ࣙ15.0° F., and 16 have produced a subcooling temperature 10.0° F.

Other References

  • "Inhibition of Crystal Growth in Methane Hydrate", Tim J. Carver, Michael G. B. Drew and P. Mark Rodger, J. Chem. Soc. Faraday Trans., Oct. 1995, 91(19), pp. 3449-346
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