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Method for modifying surfaces with ultra thin films

Patent 5897918 Issued on April 27, 1999. Estimated Expiration Date: Icon_subject December 17, 2017. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

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Method of applying thin films of amphiphilic molecules to substrates
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Mold surfaces with ultra thin release films
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Inventors

Application

No. 992146 filed on 12/17/1997

US Classes:

427/352, Liquid extraction of coating constituent or cleaning coating427/353, With water427/388.1, Metal base427/388.5, Nonaqueous dispersion427/435Metal base

Examiners

Primary: Dudash, Diana

Attorney, Agent or Firm

International Classes

B05D 001/18
B05D 003/00

Abstract

A faster and more efficient method for applying ultra thin films to substrate surfaces is disclosed. The method comprises heating a film forming composition comprising amphiphilic molecules to a liquid state, immersing the substrate surface in the heated liquid composition to heat the surface, and washing away the excess composition. For surfaces that ordinarily have insufficient or no chemical moieties reactive with the amphiphilic molecules, the immersion in the heated composition causes the substrate to become porous and expose previously unavailable chemically reactive moieties in the surface matrix. The amphiphilic molecules then self-assemble, chemically bond to the surface matrix and self-polymerize with each other and with other surface matrix-bound and/or surface-bound molecules to form the ultra thin surface film. The method is also faster and more efficient for coating non porous and metal surfaces.

Other References

  • Bigelow, W.C. et al., Oleophobic Monolayers. I. Films adsorbed from solution in non-polar liquids. J. Colloid Science 1: 513-538 (1946). (no month)
  • Lieng-Huang Lee. Wettability and Conformation of Reactive Polysiloxanes. J. Colloid and Interface Science 27(4): 751-760 (1968). Aug
  • Polymeropoulos, E.E. and Sagiv, J., Electrical Conduction Through Adsorbed Monolayers. J. Chem. Phys. 69(5): 1836-1847 (1978). Sep
  • Hawley's Condensed Chemical Dictionary, Twelfth Edition, 1993, Defn. of "Ultrasonics". (no month
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