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Oxide thin film, electronic device substrate and electronic device

Patent 5828080 Issued on October 27, 1998. Estimated Expiration Date: Icon_subject August 17, 2015. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Inventors

Assignee

Application

No. 516356 filed on 08/17/1995

US Classes:

257/43, SEMICONDUCTOR IS AN OXIDE OF A METAL (E.G., CUO, ZNO) OR COPPER SULFIDE257/310, With high dielectric constant insulator (e.g., Ta 2 O 5 )257/314, Variable threshold (e.g., floating gate memory device)257/410, Gate insulator includes material (including air or vacuum) other than SiO 2257/411, Composite or layered gate insulator (e.g., mixture such as silicon oxynitride)257/E21.193, On single crystalline silicon (EPO)257/E21.271, Composed of oxide or glassy oxide or oxide based glass (EPO)257/E21.433, Where the source and drain or source and drain extensions are self-aligned to sides of gate (EPO)257/E29.162Insulating materials for IGFET (EPO)

Examiners

Primary: Tran, Minh Loan

Attorney, Agent or Firm

Foreign Patent References

  • 63-15442 JP. 01/13/1988
  • 2-5567 JP. 01/13/1990
  • 2-82585 JP. 03/13/1990
  • 2-189969 JP. 07/13/1990
  • 2-258700 JP. 10/13/1990
  • 5-186298 JP. 07/13/1993
  • 5-218303 JP. 08/13/1993
  • 5-53069 JP. 08/13/1993
  • 5-243567 JP. 09/13/1993
  • 5-243525 JP. 09/13/1993
  • 5-283612 JP. 10/13/1993
  • 5-74949 JP. 10/13/1993
  • 6-85264 JP. 03/13/1994
  • 6-97452 JP. 04/13/1994
  • 6-97401 JP. 04/13/1994

International Classes

H01L 029/12
H01L 029/76

Foreign Application Priority Data

1994-08-17 JP

Abstract

The invention provides an oxide thin film in the form of an epitaxial film of the composition: Zr1-x Rx O2-δ wherein R is a rare earth metal inclusive of Y, x=0 to 0.75, preferably x=0.20 to 0.50, formed on a surface of a single crystal silicon substrate. A rocking curve of the film has a half-value width of up to 1.50°. The film has a ten point mean roughness Rz of up to 0.60 nm across a reference length of 500 nm. An epitaxial film of the composition ZrO2 is constructed by unidirectionally oriented crystals. When a functional film is to be formed on the oxide thin film serving as a buffer film, an adequately epitaxially grown functional film of quality is available. Particularly when the single crystal substrate is rotated within its plane, an oxide thin film of uniform high quality having an area as large as 10 cm2 or more is obtained.

Other References

  • Japanese Journal of Applied Physics, vol. 29, No. 6, pp. L955-L957, Jun. 1990, Hiroaki Myoren, et al., "Crystalline Qualities and Critical Current Densities of As-Grown Ba2YCu30x Thin Films on Silicon with Buffer Layers"
  • Applied Physics Letter, vol. 60, No. 10, pp. 1199-1201, Mar. 1992, Keiichi Nashimoto, et al., "Epitaxial Growth of MgO on GaAs(001) for Growing Epitaxial BaTiO3 Thin Films by Pulsed Laser Deposition"
  • Applied Physics Letter, vol. 55, No. 4, pp. 360-361, Jul. 24, 1989, Hirofumi Fukumoto, et al., "Heteroepitaxial Growth of Y203 Films on Silicon"
  • Journal of Applied Physics, vol. 61, No. 6, pp. 2398-2400, Mar. 15, 1987, Yuichi Kado, et al., "Heteroepitaxial Growth of SrO Films on Si Substrates"
  • Applied Physics Letter, vol. 61, No. 26, pp. 3184-3186, Dec. 28, 1992, Jianmin Qiao, et al., "Thermally Activated Reversible Threshold Shifts in YBa2Cu307-δ/ Yttria-Stabilized Zirconia/Si Capacitors"
  • Journal of Aplied Physics, vol. 63, No. 2, pp. 581-582, Jan. 15, 1988, Yukio Osaka, et al., "Evaluation of Crystalline Quality of Zirconium Dioxide Films on Silicon by Means of Ion-Beam Channeling"
  • Journal of Applied Physics, vol. 30, No. 8A, pp. L1415-L1417, Aug. 1991, Hiroyuki Mori, et al., "Expitaxial Growth of SrTiO3 Films on Si(100) Substrates using a Focused Electron Beam Evaporation Method"
  • Journal of Applied Physics, vol. 58, No. 6, pp. 2407-2409, Sep. 15, 1985, M. Morita, et al., "Growth of Crystalline Zirconium Dioxide Films on Silicon"
  • Thin Solid Films, vol. 229, No. 17, pp. 17-23, 1993, Susumu Horita, et al., "Improvement of the Crystalline Quality of an Yttria-Stabilized Zirconia Film on Silicon by a New Deposition Process in Reactive Sputtering"
  • Japanese Journal of Applied Physics, vol. 27, No. 8, pp. L1404-L1405, Aug. 1988, Hirofumi Fukumoto, et al., "Heteroepitaxial Growth of Yttria-Stabilized Zirconia (YSZ) on Silicon"
  • Applied Physics Letter, vol. 57, No. 11, pp. 1137-1139, Sep. 10, 1990, D.K. Fork, et al., "Epitaxial Yttria-Stabilized Zirconia on Hydrogen-Terminated Si by Pulsed Laser Deposition"
  • Applied Physics Letter, vol. 54, No. 8, pp. 754-756, Feb. 20, 1989, X.D. Wu, et al., "High Critical Currents in Epitaxial YBa2Cu3O7-x Thin Films on Silicon with Buffer Layers"
  • Applied Physics Letter, vol. 53, No. 16, pp. 1506-1508, Oct. 17, 1988, P. Legagneux, et al., "Epitaxial Growth of Yttria-Stabilized Zirconia Films on Silicon by Ultrahigh Vacuum Ion Beam Sputter Deposition"
  • Japanese Journal of Applied Physics, vol. 27, No. 4, pp. L634-L635, apr. 1988, Hiroyuki Nasu, et al., "Formation of High-Tc Superconducting BiSrCaCu20x Films on ZrO2/Si(100)
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