U.S. patents available from 1976 to present.
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Method of treating lithium manganese oxide spinel

Patent 5783328 Issued on July 21, 1998. Estimated Expiration Date: Icon_subject November 26, 2016. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Rechargeable organic electrolyte cell
Patent #: 4828834
Issued on: 05/09/1989
Inventor: Nagaura ,   et al.

Method for preparation of LiMn2 O4 intercalation compounds and use thereof in secondary lithium batteries
Patent #: 5135732
Issued on: 08/04/1992
Inventor: Barboux, et al.

Method of preparing LI1+XMN204 for use as secondary battery electrode
Patent #: 5266299
Issued on: 11/30/1993
Inventor: Tarascon

Nonaqueous electrolyte secondary cell
Patent #: 5370710
Issued on: 12/06/1994
Inventor: Nagaura, et al.

Method for synthesis of high capacity Lix Mn2 O4 secondary battery electrode compounds
Patent #: 5425932
Issued on: 06/20/1995
Inventor: Tarascon

Method for increasing the reversible capacity of lithium transition metal oxide cathodes
Patent #: 5449577
Issued on: 09/12/1995
Inventor: Dahn, et al.

Lithium manganese oxide compound and method of preparation Patent #: 5597664
Issued on: 01/28/1997
Inventor: Ellgen

Inventor

Assignee

Application

No. 757055 filed on 11/26/1996

US Classes:

429/137, Coating on electrode423/599, Manganese (e.g., manganate, etc.)427/126.1, Metallic compound coating429/224Manganese component is active material

Examiners

Primary: Kalafut, Stephen

Attorney, Agent or Firm

Foreign Patent References

  • 0712173 EP. 05/13/1996
  • 2276155 GB. 09/13/1994
  • 2276156 GB. 09/13/1994

International Class

H01M 004/50

Abstract

A method of treating lithium manganese oxide of spinel structure is disclosed. The method involves heating the lithium manganese oxide spinel in an atmosphere of an inert gas, e.g, argon, helium, nitrogen or carbon dioxide, which does not react with the spinel. Alternatively, the spinel may be first coated with an alkali metal hydroxide, preferably lithium, sodium or potassium hydroxide and then heated in an atmosphere preferably containing carbon dioxide. Such treatment of lithium manganese oxide spinel improves the performance of the spinel when employed as an electrode in rechargeable cells such as lithium-ion cells. Alternatively, the spinel may be first treated in an aqueous solution of a soluble metal salt of a carboxylic acid prior to treatment with heated carbon dioxide or inert gas. In such latter case the spinel may optionally also be treated with an alkali metal hydroxide prior to treatment with carbon dioxide or inert gas.

Other References

  • D.G. Wickham and W.J. Croft. J. Phys. Chem. Solids. vol. 7. p. 351 (1958) (Month Unknown
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