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US Patent 5773632 - Process for the preparation of the enol lactone of 2-oxocyclohexlidene acetic acid and application to the preparation of 2-cuomaranone

US Patent Issued on June 30, 1998
Estimated Patent Expiration Date: Icon_subject June 26, 2017Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.
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Abstract

A process for the preparation of the enol lactone of 2-oxocyclohexylidene acetic acid wherein(i) glyoxylic acid is allowed to react with cyclohexanone in the presence of a halogen acid in order to obtain a crude reaction product B1, then(ii) said crude reaction product B1 is allowed to react, after solubilisation in an organic solvent, in the presence of a strong acid soluble in said organic solvent or of strongly acid resins, in order to obtain the enol lactone of 2-oxocyclohexylidene acetic acid which is isolated if desired,and application to the preparation of 2-coumaranone.

Inventors

Assignee

Application

No. 883594 filed on 06/26/1997

US Classes:

549/307, The other cyclo of the bicyclo ring system is benzene (e.g., phthalides, etc.)549/462, Bicyclo ring system having the hetero ring as one of the cyclos549/471Plural double bonds between ring members of the hetero ring

Field of Search

549/307, The other cyclo of the bicyclo ring system is benzene (e.g., phthalides, etc.)549/462, Bicyclo ring system having the hetero ring as one of the cyclos549/471Plural double bonds between ring members of the hetero ring

Examiners

Primary: Trinh, Ba K.

Attorney, Agent or Firm

US Patent References

3862133

Foreign Patent References

  • 2 721 609 FR. 12/21/1995
  • 1 184 774 DD. 01/21/1965
  • 0 584 372 DE. 09/21/2010
  • 1 337 507 GB. 11/21/1973

International Class

C07D 307/83

Foreign Application Priority Data

1996-07-09 FR

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