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Method of producing sugars using strong acid hydrolysis

Patent 5726046 Issued on March 10, 1998. Estimated Expiration Date: Icon_subject July 2, 2016. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Process for the acid hydrolysis of carbohydrate polymers and the continuous fermentation of the sugars _obtained therefrom to provide ethanol
Patent #: 4242455
Issued on: 12/30/1980
Inventor: Muller ,   et al.

Conversion of cellulosic fibers to mono-sugars and lignin
Patent #: 4427584
Issued on: 01/24/1984
Inventor: LeGrand ,   et al.

Acid hydrolysis of biomass for alcohol production
Patent #: 4612286
Issued on: 09/16/1986
Inventor: Sherman ,   et al.

Process for production of xylitol from lignocellulosic raw materials
Patent #: 4742814
Issued on: 05/10/1988
Inventor: Sinner ,   et al.

Process for the production of fermentable sugars from biomass
Patent #: 4880473
Issued on: 11/14/1989
Inventor: Scott, et al.

Method for recovering xylose
Patent #: 5084104
Issued on: 01/28/1992
Inventor: Heikkila, et al.

Concentrated sulfuric acid process for converting lignocellulosic materials to sugars
Patent #: 5188673
Issued on: 02/23/1993
Inventor: Clausen, et al.

Method of producing sugars using strong acid hydrolysis of cellulosic and hemicellulosic materials
Patent #: 5562777
Issued on: 10/08/1996
Inventor: Farone, et al.

Strong acid hydrolysis of cellulosic and hemicellulosic materials Patent #: 5597714
Issued on: 01/28/1997
Inventor: Farone, et al.

Inventors

Assignee

Application

No. 674405 filed on 07/02/1996

US Classes:

435/100, Disaccharide127/1, Hydrolyzing127/36, Hydrolysis of carbohydrates127/37, Cellulose material127/46.2, Involving ion manipulation, e.g., ion exchange, etc.127/46.3, For ion exclusion210/665, By making an insoluble substance or accreting suspended constituents210/673, Utilizing gas, water, or chemical oxidizing or reducing agent423/335, Silica423/339, By precipitating435/99, Produced by the action of a carbohydrase (e.g., maltose by the action of alpha amylase on starch, etc.)435/105, Monosaccharide435/161, Ethanol435/168, Preparing element or inorganic compound except carbon dioxide435/171, Using fungi435/803, PHYSICAL RECOVERY METHODS (E.G., CHROMATOGRAPHY, GRINDING)435/911, Using fungi435/921, Candida536/1.11, Carbohydrates or derivatives536/124, Processes536/127Purification or recovery

Examiners

Primary: Lilling, Herbert J.

Attorney, Agent or Firm

Foreign Patent References

  • 859449 SU. 08/25/1981

International Classes

C13K 001/02
C12P 019/12
C12P 019/02

Abstract

A economically viable method for producing sugars using concentrated acid hydrolysis of biomass containing cellulose and hemicellulose is disclosed. The cellulose and hemicellulose in the biomass is first decrystallized and then hydrolyzed to produce a hydrolysate containing both sugars and acid. Silica and silicates present in the biomass can then be removed for further processing. The remaining solids are then subjected to a second decrystallization if necessary and a second hydrolyzation to optimize the sugar yields.

Other References

  • "Integrated Fuel Alcohol Productin Systems, Phase III" Barrier, et al., Experimental Facility Testing Report for Jan. 15, 1985-Jan. 15, 1986
  • "Process Considerations for Scale-up of Liquid Chromatography and Electrophoresis" Rudge, et al., Separation, Recovery, and Purification in Biotechnology, pp. 122-152 (1986)
  • "Application of Continuous Substrate Feeding to the ABE Fermentation: Relief of Product Inhibition Using Extraction, Perstraction, Stripping, and Pervaporation" Qureshi, et al., Biotechnol. Prog., 8: No. 5, pp. 382-390 (1992)
  • "Concentrated Sulfuric Acid Processes" Fan, et al., Cellulose Hydrolysis, Section 5.2.2, pp. 170-172 (Date unknown)
  • "Conversion of Cotton Trash and Other Residues to Liquid Fuel" Broder, et al., pp. 189-200 (Publication and date unknown)
  • "Ethanol from Biomass by Concentrated Acid Hydrolysis and Fermentation" Clausen. Ph.D., et al., pp. 1319-1342 (Publication and date unknown
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