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Static dissipative composition and process for static disspative coatings

Patent 5716551 Issued on February 10, 1998. Estimated Expiration Date: Icon_subject February 9, 2016. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Electrically conductive polymeric compositions
Patent #: 4293452
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Inventor: Fox ,   et al.

Solution processible forms of neutral and electrically conductive poly(substituted heterocycles)
Patent #: 4711742
Issued on: 12/08/1987
Inventor: Jen ,   et al.

Electron-donor dopant, method of improving conductivity of polymers by doping therewith, and a polymer so treated
Patent #: 4755326
Issued on: 07/05/1988
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Antistatic floor polish
Patent #: 4872910
Issued on: 10/10/1989
Inventor: Eshleman, et al.

UV curable temporary solder mask
Patent #: 5420171
Issued on: 05/30/1995
Inventor: Unruh

Electrically-conductive and ionically-conductive polymeric networks and their preparation Patent #: 5462696
Issued on: 10/31/1995
Inventor: McGinniss, et al.

Inventors

Assignee

Application

No. 599295 filed on 02/09/1996

US Classes:

252/500, ELECTRICALLY CONDUCTIVE OR EMISSIVE COMPOSITIONS427/487, Polymerization of coating utilizing direct application of electrical, magnetic, wave, or particulate energy (i.e., including cross-linking, curing, and hardening of organics)427/508, Low energy electromagnetic radiation utilized (e.g., UV, visible, IR, microwave, radio wave, actinic, laser, etc.)427/516, Coating is adhesive or is intended to be made adhesive (e.g., release sheet or coating, etc.)522/6, Compositions to be polymerized or modified by wave energy wherein said composition contains at least one specified rate-affecting material; or processes of preparing or treating a solid polymer utilizing wave energy in the presence of at least one specified rate-affecting material; e.g., nitrogen containing photosensitizer, oxygen containing photoinitiator, etc. wave energy in order to prepare a cellular product522/74, Organic DNRM522/83, Oxygen containing DNRM522/109Processes of chemically modifying a blend of two or more solid polymers in the presence of a chemical reactant; or compositions therefore

Examiners

Primary: Lieberman, Paul
Assistant: Kopec, M.

Attorney, Agent or Firm

International Classes

H01B 001/124
C08F 002/48

Abstract

A U.V. curable composition for application to a substrate surface to provide a static dissipative coating which comprises a conductive matrix constituent having a crown type ligand selected from the group consisting of podands, coronands and cryptands in a guest/host relationship with a conductive dopant moiety. Such ligands included those provided by functionalized podands and functionalized coronands. The formulation further includes a polymer matrix constituent formed of a base oligomer system and a crosslinking agent which is reactive with the base oligomer system to form a crosslinked resin matrix which incorporates the conductive matrix constituent. A low viscosity diluent functions as a solvating liquid for the crosslinking agent and the base oligomer system. The formulation further includes a photoinitiator of the free radical or cationic type to initiate polymerization of the composition upon the application of electromagnetic radiation in the ultraviolet range. The low viscosity diluent liquid may be reactive with the base oligomer system and the crosslinking agent when it is cured under UV radiation. A specific conductive matrix constituent is an acrylated or unsubstituted coronand in a guest/host relationship with an alkali metal ion selected from the group consisting of lithium, sodium and potassium. A method for treating a solid surface to produce a static dissipative surface by application of a clear liquid coating material comprising a conductive matrix constituent and a conductive dopant moiety and other components as described above. The coating liquid is applied to a substrate surface to provide a liquid film on the surface and is irradiated with ultraviolet radiation to effect crosslinking of the polymerizable matrix constituent to provide a cured transparent film having a surface resistivity of 105 -1014 ohms per square.

Other References

  • Wu Chang Pei et al, "Study on Preparation of UV Cross-Linking Films of Polyurethane-LiClO4 Complexes and Their Ionic Conductivity,"Acta Physica Sinica (Overseas Edition), vol. 2, No. 11, pp. 841-849, Science Press, Nov. 1993
  • Host Guest Complex Chemistry Macrocycles; Synthesis, Structures, Applications, pp. 1-41, F. Vogtle et al, editors, Springer-Verlag, New York, 1985
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