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US Patent 5714391 - Method of manufacturing a compound semiconductor thin film for a photoelectric or solar cell device

US Patent Issued on February 3, 1998
Estimated Patent Expiration Date: Icon_subject May 16, 2016Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.
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Abstract

This invention relates to a manufacturing method of a compound semiconductor thin film derived from a metal sulfide produced by thermal decomposition of a sulfur-containing metal organic compound, the compound containing at least one functional group having at least one metal atom selected from the group consisting of copper, zinc, cadmium, mercury, and lead, and the functional group also containing at least one sulfur atom. Since the obtained metal sulfides are of high-purity and dense, they can be utilized in various photoelectric devices. Particularly, the photoelectric conversion efficiency of a CdS/CdTe system thin film compound semiconductor solar cell can be improved remarkably by employing a layer made of a CdS thin film as a window of the solar cell.

Other References

  • Pande et al., "Electrophoretically Deposited CdTe Films and CdS-CdTe Devices", 13th European Photovoltaic Solar Energy Conference and Exhibition; Nice, France, Oct. 23, 1995-Oct. 27, 1995
  • Kessler et al., "Characterization of High Vacuum Evaporated CdTe/CdS Layers and Solar Cells", 13th European Photovoltaic Solar Energy Conference and Exhibition; Nice, France Oct. 23, 1995-Oct. 27, 1995
  • Chu et al., "Recent Progress in Thin-film Cadmium Telluride Solar Cells", Progress in Photovoltaics: Research and Applications, vol. 1, pp. 31-42 (1993

Inventors

Assignee

Application

No. 648544 filed on 05/16/1996

US Classes:

438/99, HAVING ORGANIC SEMICONDUCTIVE COMPONENT136/244, Panel or array136/260, Cadmium containing136/264, Selenium or tellurium containing136/265, Copper, lead, or zinc containing257/E31.007, Comprising only heterojunction including Group I-III-VI compound (e.g., CdS/CuInSe 2 heterojunction) (EPO)427/74, Photoelectric427/226, HEAT DECOMPOSITION OF APPLIED COATING OR BASE MATERIAL427/255.33, Zinc (Zn), cadmium (Cd), or mercury (Hg), containing427/255.35Germanium (Ge), tin (Sn), or lead (Pb) containing

Field of Search

136/260, Cadmium containing136/264, Selenium or tellurium containing136/265, Copper, lead, or zinc containing257/184, Light responsive structure427/74, Photoelectric427/226, HEAT DECOMPOSITION OF APPLIED COATING OR BASE MATERIAL427/248.1, COATING BY VAPOR, GAS, OR SMOKE427/372.2Heating or drying (e.g., polymerizing, vulcanizing, curing, etc.)

Examiners

Primary: Weisstuch, Aaron

Attorney, Agent or Firm

US Patent References

4360542, Process for the preparation of thin films of cadmium sulfide and precursor solutions of cadmium ammonia thiocyanate complex useful therein
Issued on: 11/23/1982
Inventor: Loeffler ,   et al.
4611091, CuInSe2 thin film solar cell with thin CdS and transparent window layer
Issued on: 09/09/1986
Inventor: Choudary ,   et al.
4734381, Method of making a thin film cadmium telluride solar cell
Issued on: 03/29/1988
Inventor: Mitchell
4975299, Vapor deposition process for depositing an organo-metallic compound layer on a substrate
Issued on: 12/04/1990
Inventor: Mir, et al.
5304499, Methods of making pn CdTe/CdS thin film solar cells
Issued on: 04/19/1994
Inventor: Bonnet, et al.
5393675Process for RF sputtering of cadmium telluride photovoltaic cell
Issued on: 02/28/1995
Inventor: Compaan

Foreign Patent References

  • 56-28386 JP 07/20/1981

International Class

H01L 031/18

Foreign Application Priority Data

1995-05-17 JP

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