U.S. patents available from 1976 to present.
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Methods of decomposing gas hydrates

Patent 5713416 Issued on February 3, 1998. Estimated Expiration Date: Icon_subject October 2, 2016. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3103973

3388744

Method of obtaining increased production in wells
Patent #: 3930539
Issued on: 01/06/1976
Inventor: Curtis

Method for production of hydrocarbons from hydrates
Patent #: 4424866
Issued on: 01/10/1984
Inventor: McGuire

Inhibition of hydrate formation
Patent #: 4856593
Issued on: 08/15/1989
Inventor: Matthews ,   et al.

Method of transporting a hydrate forming fluid
Patent #: 4915176
Issued on: 04/10/1990
Inventor: Sugier, et al.

Gas hydrate inhibition Patent #: 5076364
Issued on: 12/31/1991
Inventor: Hale, et al.

Inventors

Assignee

Application

No. 720825 filed on 10/02/1996

US Classes:

166/263, Cyclic injection then production of a single well166/300, Chemical inter-reaction of two or more introduced materials (e.g., selective plugging or surfactant)166/303, Placing preheated fluid into formation166/308.2, Using a chemical (EPO)166/312, Liquid introduced from well top166/371, Including non-expulsive material placed in well423/580.1, Water585/15HYDRATE OR PRODUCTION THEREOF

Examiners

Primary: Suchfield, George A.

Attorney, Agent or Firm

International Classes

E21B 043/24
E21B 043/26

Abstract

The present invention provides methods of decomposing gas hydrates in subsea or subterranean wells, the equipment associated with the wells and in subterranean reservoirs containing gas hydrates. The methods basically comprise the steps of combining an acidic liquid with a basic liquid which chemically react exothermically to form a hot salt solution, contacting the gas hydrates with the hot salt solution to decompose at least a portion of the gas hydrates whereby natural gas and water are released therefrom and recovering the released natural gas, water and salt solution.

Other References

  • Donald L. Katz, "Depths to Which Frozen Gas Fields (Gas Hydrates) May Be Expected," Journal of Petroleum Technology, pp. 419-423, Apr., 1971
  • G.D. Holder, P.F. Angert, V.T. John and S. Yen, "A Thermodynamic Evaluation of Thermal Recovery of Gas From Hydrates in the Earth," Journal of Petroleum Technology, pp. 1127-1132, May, 1982
  • T.S. Collett and C.A. Ehlig-Economides, "Detection and Evaluation of the In-Situ Natural Gas Hydrates in the North Slope Region, Alaska," SPE Paper No. 11673, presented at the 1983 California Regional Meeting held in Ventura, California, Mar. 23-25, 1983
  • K.A. Kvenvolden, "Gas Hydrates at Two Sites of an Active Continental Margin," SPE Paper No. 13592, presented at the SPE 1985 California Regional Meeting held in Bakersfield, California, Mar. 27-29, 1985
  • Vidyadhar A. Kamath and Sanjay P. Godbole, "Evaluation of Hot-Brine Stimulation Technique for Gas Production From Natural Gas Hydrates," Journal of Petroleum Technology, pp. 1379-1388, Nov., 1987
  • S.P. Godbole, V.A. Kamath and C. Ehlig-Economides, "Natural Gas Hydrates in the Alaskan Arctic," SPE Formation Evaluation, pp. 263-266, Mar., 1988
  • D.T. Lai and A.K. Dzialowski, "Investigation of Natural Gas Hydrates in Various Drilling Fluids," SPE/IADC Paper No. 18637, prepared for presentation at the 1989 SPE/IADC Drilling Conference held in New Orleans, Louisiana, Feb. 28-Mar. 3, 1989
  • Arthur H. Hale and Ashok K.R. Dewan, "Inhibition of Gas Hydrates in Deepwater Drilling," SPE Drilling Engineering, pp. 109-115, Jun., 1990
  • T.S. Kotkoskie, B. Al-Ubaidi, T.R. Wildeman and E.D. Sloan, "Inhibition of Gas Hydrates in Water-Based Drilling Muds," SPE Paper No. 20437, prepared for presentation at the 65th Annual Technical Conference and Exhibition of the Society of Petroleum Engineers held in New Orleans, Louisiana, Sep. 23-26, 1990
  • J-C. Iseux, "Gas Hydrates: Occurrence, Production and Economics," SPE Paper No. 21682, prepared for presentation at the Production Operations Symposium held in Oklahoma City, Oklahoma, Apr. 7-9, 1991
  • M.R. Islam, "A New Recovery Technique for Gas Production From Alaskan Gas Hydrates," SPE Paper No. 22924, prepared for presentation at the 66th Annual Technical Conference and Exhibition of the Society of Petroleum Engineers held in Dallas, Texas, Oct. 6-9, 1991
  • R.B. Grigg and G.L. Lynes, "Oil-Based Drilling Mud as a Gas-Hydrates Inhibitor," SPE Drilling Engineering, pp. 32-38, Mar. 199
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