U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Process for purifying, uncapping and chemically modifying carbon nanotubes

Patent 5698175 Issued on December 16, 1997. Estimated Expiration Date: Icon_subject July 3, 2015. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Treatment of carbon fibers
Patent #: 3989802
Issued on: 11/02/1976
Inventor: Joo ,   et al.

Process for the surface treatment of carbon fibers
Patent #: 4009305
Issued on: 02/22/1977
Inventor: Fujimaki ,   et al.

Process for production of a carbon filament
Patent #: 4816289
Issued on: 03/28/1989
Inventor: Komatsu ,   et al.

Uncapped and thinned carbon nanotubes and process Patent #: 5346683
Issued on: 09/13/1994
Inventor: Green, et al.

Inventors

Assignee

Application

No. 497895 filed on 07/03/1995

US Classes:

423/447.1, Fiber, fabric, or textile423/445B, Fullerene (e.g., C60, C70, etc.)423/460, Treating carbon423/461Recovery or purification

Examiners

Primary: Bos, Steven
Assistant: DiMauro, Peter

Attorney, Agent or Firm

Foreign Patent References

  • 6-157016 JP. 02/13/2012
  • 6-153192 JP. 02/13/2012

International Classes

C01B 031/00
D01F 009/12

Foreign Application Priority Data

1994-07-05 JP

Abstract

Disclosed is a process for purifying carbon nanotubes which has steps of 1) mixing carbon nanotubes which accompany carbon impurities with a reagent selected from a group consisting of oxidation agents, nitration agents and sulfonation agents in liquid phase, 2) reacting the carbon nanotubes with the reagent at a predetermined temperature in the liquid phase, wherein the carbon impurities except carbon nanotubes are selectively reacted to dissolve in the liquid phase, and 3) separating carbon nanotubes from which the impurities were released from the liquid phase then washing and drying it. A process for uncapping carbon nanotubes and a process for chemically modifying carbon nanotubes are also disclosed.

Other References

  • T.W. Ebbesen, et al, Purification of nanotubes, Nature International Weekly Journal of Science, Feb. 10, 1994
  • P.M. Ajayan, et al, Opening carbon nanotubes with oxygen and implications for filling, Nature International Weekly Journal of Science, Apr. 8, 1993
  • S.C. Tsang, et al, Thinning and opening of carbon nanotubes by oxidation using carbon dioxide, Letters to Nature, Apr. 8, 1993
  • T.W. Ebbesen, et al, Large-scale synthesis of carbon nanotubes, Nature International Weekly Journal of Science, Jul. 16, 1992
  • Tsang, S.C., et al. "A simple chemical Method of Opening and Filling Carbon Nanotubes", Nature, vol. 372, 10 Nov. 1994, pp. 159-16
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