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Growth of doped semiconductor monolayers

Patent 5693139 Issued on December 2, 1997. Estimated Expiration Date: Icon_subject December 2, 2014. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Inventors

Assignee

Application

No. 077119 filed on 06/15/1993

US Classes:

117/89, Including change in a growth-influencing parameter (e.g., composition, temperature, concentration, flow rate) during growth (e.g., multilayer or junction or superlattice growing)117/93, With significant flow manipulation or condition, other than merely specifying the components or their sequence or both117/102, With significant flow manipulation or condition, other than merely specifying the components or their sequence or both117/105, Including change in a growth-influencing parameter (e.g., composition, temperature, concentration, flow rate) during growth (e.g., multilayer or junction or superlattice growing)117/953, {B,Al,Ga,In,Tl}{P,As,Sb,Bi} compound containing, except intermetallics thereof (i.e., except {Al,Ga,In,Tl}{Sb,Bi}) {C30B 29/40}117/954, Gallium arsenide containing (e.g., GaAlAs, GaAs) {C30B 29/42}117/956, {Zn,Cd,Hg}{S,Se,Te} compound containing {C30B 29/46}257/E21.09, Deposition of semiconductor material on substrate, e.g., epitaxial growth, solid phase epitaxy (EPO)257/E21.11, Doping the epitaxial deposit (EPO)257/E21.123, Substrate is crystalline semiconductor material, e.g., lattice adaptation, heteroepitaxy (EPO)257/E21.131Selective epilaxial growth, e.g., simultaneous deposition of mono- and non-mono semiconductor material (EPO)

Examiners

Primary: Kunemund, Robert

Attorney, Agent or Firm

International Class

C30B 025/14

Foreign Application Priority Data

1984-07-26 JP

Abstract

A cycle of alternately or cyclically introducing external gases containing molecules of component elements of a compound semiconductor to be formed on a substrate is repeated while appropriately controlling the pressure, substrate temperature and gas introduction rate in a crystal growth vessel, so that a monocrystal which is dimensionally as precise as a single monolayer can grow on the substrate by making use of chemical reactions on the heated substrate surface.Doped molecular layer epitaxy of a compound semiconductor comprising individual steps of introducing and evacuating a first source gas, introducing and evacuating a second source gas, and introducing and evacuating an impurity gas which contains an impurity element. The doped impurity concentration varies almost linearly with the pressure during doping in a wide range.

Other References

  • Tohru Kurabayashi et al., "Photoexcited Molecular Layer Epitaxial Growth Process of GaAs, GaAs and Si, and Photo-Vapor-Epitaxy of GaAs", Collected Summaries of Researches (published for Research Development Corporation of Japan), Dec. 19, 1986, cover pages and pp. 1-24 all in Japanese (An English translation of the pertinent pp. 13-14 is attached.)
  • Junichi Nishizawa et al., "Molecular Layer Epitaxy", Semiconductor Research, vol. 29 (published for Industrial Survey under the Foundation for Promoting Semiconductor Research), Aug. 22, 1987, cover page and p. 97-136 all in Japanese (An English translation of the pertinent pp. 98 to 103 is attached.)
  • Tohru Kurabayashi, "Photo-Assisted Molecular Layer Epitaxy", Semiconductor Research, vol. 33 (published for Industrial Survey under the Foundation for Promoting Semiconductor Research, Aug. 8, 1989, cover page and 33 pags all in Japanese (An English translation of the pertinent pp. 4-6 is attached.)
  • Junichi Nishizawa, "Crystal Growth by Atomic Layer Epitaxy"Applied Physics, vol. 53, No. 6 (1984), (An English translation of the pertinent pp. 516-519 is attached.
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