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Ultra-flexible retroreflective cube corner composite sheetings and methods of manufacture

Patent 5691846 Issued on November 25, 1997. Estimated Expiration Date: Icon_subject June 7, 2015. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

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Inventors

Application

No. 472444 filed on 06/07/1995

US Classes:

359/530, Unitary plate or sheet comprising plural reflecting elements156/245, In configured mold264/214, To form nonplanar article or surface359/529, 3-Corner retroreflective (i.e., cube corner, trihedral, or triple reflector type)359/900, METHODS428/172Composite web or sheet

Examiners

Primary: Phan, James

Attorney, Agent or Firm

Foreign Patent References

  • 0 175 031 A1 EP. 03/23/1986
  • A 0 200 521 EP. 11/23/1986
  • 0 382 420 A2 EP. 08/23/1990
  • 0 478 178 A1 EP. 04/23/1992
  • 2 245 219 GB. 01/23/1992
  • WO 92/04647 WO. 03/23/1992
  • WO 94/19711 WO. 09/23/1994
  • WO 95/03558 WO. 02/23/1995
  • WO 95/07179 WO. 03/23/1995
  • WP 95/11466 WO. 04/23/1995

International Class

G02B 005/124

Abstract

A method for manufacturing flexible cube corner retroreflective sheeting comprising the steps of:a) providing a tool having a molding surface;b) applying to the molding surface a volume of a flowable resin composition;c) contacting the resin composition with a first major surface of an overlay film;d) minimizing excess resin composition;e) curing the resin composition to form a sheeting comprising an array of cube corner elements bonded to the overlay film;f) removing the sheeting from the tool; andg) applying mechanical stress to the sheeting so as to cause a fractured separation of substantially each individual cube corner element from surrounding cube corner elements. Also, flexible retroreflective sheetings comprising: a) a two dimensional array of substantially independent cube corner elements, the array comprising a first polymeric material, and b) an overlay film having two major surfaces and comprising of a second polymeric material, the array being bonded to the first major surface of the overlay film. Also safety devices incorporating such sheetings.

Other References

  • Yoder, P.R. Jr., "Study of Light Deviation Errors in Triple Mirrors and Tetrahedral Prisms," J. Optical Soc. of America, vol. 48, No. 7, Jul. 1959, pp. 496-499
  • Leighton, J. et al., "RF Welding and PVC and Other Thermoplastic Compounds," ANTEC, 1992, pp. 724-728
  • Priola, A., et al., Proceedings of the XIII International Conference in Organic Coatings Science and Technology, Athens, Greece, Jul. 7-11, 1987, pp. 308-31
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