U.S. patents available from 1976 to present.
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Process for the preparation of synthetic resin dispersions

Patent 5679735 Issued on October 21, 1997. Estimated Expiration Date: Icon_subject December 22, 2015. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

2795564

3054762

3423352

3442844

3491039

Preparation of aqueous polyacrylate dispersions having improved flow characteristics
Patent #: 4265796
Issued on: 05/05/1981
Inventor: Mueller-Mall ,   et al.

Process for the manufacture of copolymers having increased resistance against hydrolysis, the copolymers and their use
Patent #: 4397968
Issued on: 08/09/1983
Inventor: Eck ,   et al.

Polyacrylate dispersions
Patent #: 4659771
Issued on: 04/21/1987
Inventor: Craig

Polyacrylate dispersions Patent #: 4670505
Issued on: 06/02/1987
Inventor: Craig

Inventors

Application

No. 577551 filed on 12/22/1995

US Classes:

524/459, Solid polymer utilized contains vinyl alcohol units524/460, Solid polymer utilized is derived from an unsaturated carboxylic acid or salt524/733, Cellulose or derivative, e.g., cotton, paper pulp, etc.524/773, Carboxylic acid or derivative not containing a heavy metal atom as DNRM, e.g., anhydride, acyl halide, ester or salt, etc.526/81, Added material is other than monomer per se, or composition containing monomer526/86, Adding catalyst or catalyst component526/87, Adding monomer526/200, Material contains carbohydrate, e.g., starch, sugar, etc.526/201, Material contains previously formed normally solid polymer which is distinct from polymer to be formed and is a polymer formed from at least one ethylenic monomer526/202, Normally solid polymer contains free alcohol group or alcoholate thereof526/203Normally solid polymer is formed from ethylenically unsaturated dicarboxylic acid, ester, salt, or anhydride thereof

Examiners

Primary: Szekely, Peter

Attorney, Agent or Firm

Foreign Patent References

  • 2127919 CA. 03/12/1995
  • 0 226 527 EP. 06/12/1987
  • 0 538 571 EP. 04/12/1993
  • 1 278 813 GB. 06/12/1972
  • 2 049 712 GB. 12/12/1980

International Classes

C08F 002/24
C08V 005/101
C08L 033/12
C08L 031/04

Foreign Application Priority Data

1994-12-24 DE

Abstract

A process for the preparation of a synthetic resin dispersion stabilized by a protective colloid employing at least one initiator and based on a polymer of (a) a first monomer of at least one ester of acrylic acid or methacrylic acid and an alcohol containing 1 to 22 carbon atoms; and optionally, (b) a second monomer which can be copolymerized with the first monomers. The process comprises introducing at least 50% of the monomers based on the total weight of the monomers, at least 50% of the protective colloid based on the total weight of the protective colloid, and up to 50% of the initiator based on the total weight of the initiator into a reaction vessel to form an aqueous emulsion. Any remaining monomers and protective colloid and at least 50% of the initiator based on the total weight of the initiator are then added to the reaction vessel at a temperature of 30° to 100° C.

Other References

  • Puterman et al., "Latex Preparation and Stabilization by Hydrophobically Modified Hydroxyethyl Celluloses", Journal of Applied Polymer Science, vol. 40, 333-343, (1990)
  • Chemical Abstracts, vol. 112, No. 4, "Emulsion Polymerization and Copolymerization of Vinyl and Acrylate Monomers", Abstract No. 21424, (1990
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