U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Process for preparing high molecular weight polyesters

Patent 5663281 Issued on September 2, 1997. Estimated Expiration Date: Icon_subject July 30, 2016. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

High molecular weight linear polyesters and method for their preparation
Patent #: 4590259
Issued on: 05/20/1986
Inventor: Kosky ,   et al.

Process for increasing the direct esterification reaction rate of a diacid with a glycol Patent #: 5015759
Issued on: 05/14/1991
Inventor: Lowe

Inventor

Assignee

Application

No. 688477 filed on 07/30/1996

US Classes:

528/272, From di- or higher ester of a polycarboxylic acid as sole reactant, or from a polycarboxylic acid or derivative with a compound containing two or more hydroxyl groups or salts thereof528/176, With polycarboxylic acid or derivative as reactant528/190, Reactant contains a fused- or bridged-ring other than solely as a polycarboxylic acid anhydride group528/191, Reactant contains a halogen atom other than solely as halogen atom bonded to a carbonyl group528/192, Ethylenically unsaturated reactant528/193, Two or more phenolic reactants528/194, Two or more polycarboxylic acids or derivatives as reactants528/271FROM CARBOXYLIC ACID OR DERIVATIVE THEREOF

Examiners

Primary: Mosley, Terressa

Attorney, Agent or Firm

Foreign Patent References

  • 6-172503 JP 06/13/1994
  • 08059810 JP 03/13/1996

International Class

C08G 063/02

Abstract

An improved process for preparing high molecular weight polyester polymers, such as poly(butylene terephthalate), an alkylene glycol and a di- or tricarboxylic acid by first preparing a pre-polymer in the form of uniform solid particles having an intrinsic viscosity of from 0.1 to about 0.3 dL/gm and a chemical composition which contains greater than a 1% stoichiometric excess of the alkylene glycol above the amount required to produce a high molecular weight polymer, and polymerizing the pre-polymer in the solid state.

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