Patent ReferencesHigh molecular weight linear polyesters and method for their preparation Process for increasing the direct esterification reaction rate of a diacid with a glycol Patent #: 5015759 InventorAssigneeApplicationNo. 688477 filed on 07/30/1996US Classes:528/272, From di- or higher ester of a polycarboxylic acid as sole reactant, or from a polycarboxylic acid or derivative with a compound containing two or more hydroxyl groups or salts thereof528/176, With polycarboxylic acid or derivative as reactant528/190, Reactant contains a fused- or bridged-ring other than solely as a polycarboxylic acid anhydride group528/191, Reactant contains a halogen atom other than solely as halogen atom bonded to a carbonyl group528/192, Ethylenically unsaturated reactant528/193, Two or more phenolic reactants528/194, Two or more polycarboxylic acids or derivatives as reactants528/271FROM CARBOXYLIC ACID OR DERIVATIVE THEREOFExaminersPrimary: Mosley, TerressaAttorney, Agent or FirmForeign Patent References
International ClassC08G 063/02AbstractAn improved process for preparing high molecular weight polyester polymers, such as poly(butylene terephthalate), an alkylene glycol and a di- or tricarboxylic acid by first preparing a pre-polymer in the form of uniform solid particles having an intrinsic viscosity of from 0.1 to about 0.3 dL/gm and a chemical composition which contains greater than a 1% stoichiometric excess of the alkylene glycol above the amount required to produce a high molecular weight polymer, and polymerizing the pre-polymer in the solid state.Field of SearchWith polycarboxylic acid or derivative as reactantReactant contains a fused- or bridged-ring other than solely as a polycarboxylic acid anhydride group Reactant contains a halogen atom other than solely as halogen atom bonded to a carbonyl group Ethylenically unsaturated reactant Two or more phenolic reactants Two or more polycarboxylic acids or derivatives as reactants FROM CARBOXYLIC ACID OR DERIVATIVE THEREOF From di- or higher ester of a polycarboxylic acid as sole reactant, or from a polycarboxylic acid or derivative with a compound containing two or more hydroxyl groups or salts thereof | |