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Method of making superhard mechanical microstructures

Patent 5658710 Issued on August 19, 1997. Estimated Expiration Date: Icon_subject February 24, 2015. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

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Inventor

Assignee

Application

No. 395410 filed on 02/24/1995

US Classes:

430/320, Making named article216/2, ETCHING OF SEMICONDUCTOR MATERIAL TO PRODUCE AN ARTICLE HAVING A NONELECTRICAL FUNCTION216/11, FORMING OR TREATING AN ARTICLE WHOSE FINAL CONFIGURATION HAS A PROJECTION427/249.15, Silicon and carbon containing coating (e.g., silicon carbide, etc.)427/255.26, Coating formed by reaction of vaporous or gaseous mixture with a base (i.e., reactive coating of non-metal base)427/355Solid treating member or material contacts coating

Examiners

Primary: McPherson, John A.

Attorney, Agent or Firm

International Class

C23C 026/00

Abstract

The forming of superhard, durable and inert mechanical microstructures, such as tips for atomic force microscopy and field emission, membranes, hinges, actuators, and sensors requires micromachining of silicon or polysilicon. The microstructures are then reacted with a hydrocarbon or ammonia gas, at a temperature in the range of 700° C. to 1100° C. and in partial vacuum conditions for several minutes. Gases such as methane, ethane, or acetylene will convert the surface layers to SiC, which is useful for its conductive properties, while ammonia gas will convert the surface layers to Si3 N4, which is useful for its insulative properties. Thus, the converted material will have improved physical, mechanical, chemical and electrical properties.

Other References

  • Gary Stix, "Micron Machinations", Scientific American, Nov. 1992 pp. 106-117
  • J. Graul and E. Wagner, "Growth mechanism of polycrystalline ଲ-SiC layers on silicon substrate", Applied Physics Letters 56, vol. 21, No. 2, pp. 67 (1972)
  • C.J. Mogab and H.J. Leamy, "Conversion of Si to epitaxial SiC by reaction with C2 H2 ", Applied Physics Letters, vol. 45, No. 3, p. 1075 (1974)
  • J. Liu et al., "Modification of Si field emitter surfaces by chemical conversion to SiC", J.Vac.Sci.Technol.B, vol. 12, No. 2 Mar./Apr. 1994
  • R. B. Marcus et al., "Formation of silicon tips with < 1 nm radius", Appl. Phys. Lett., vol. 56, No. 3, pp. 236-238 (15 Jan. 1990
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