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Method of purifying carbon nanotubes

Patent 5641466 Issued on June 24, 1997. Estimated Expiration Date: Icon_subject June 24, 2014. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Uncapped and thinned carbon nanotubes and process Patent #: 5346683
Issued on: 09/13/1994
Inventor: Green, et al.

Inventors

Assignee

Application

No. 253168 filed on 06/02/1994

US Classes:

423/447.2, Product423/445B, Fullerene (e.g., C60, C70, etc.)423/447.1, Fiber, fabric, or textile423/461Recovery or purification

Examiners

Primary: Straub, Gary P.
Assistant: DiMauro, Peter

Attorney, Agent or Firm

International Classes

C01B 031/00
D01F 009/12

Foreign Application Priority Data

1993-06-03 JP

Abstract

A mixture of carbon nanotubes and impurity carbon materials, which include carbon nanoparticles and may possibly include amorphous carbon, is purified into carbon nanotubes of high purity by utilizing a significant difference in oxidizability between the nanotubes and the nanoparticles. The mixture is pulverized and heated in the presence of an oxidizing agent at a temperature in the range from 600° to 1000° C. until the impurity carbon materials are oxidized and dissipated into gas phase. The nanotubes remain almost unoxidized except for loss of some lengths from the tube tips. It is suitable to perform the heating in air or oxygen.

Other References

  • Saxby, J., et al. "Thermogravimetric Analysis of Buckminster Fullerene and Related Materials in Air", J. Phys. Chem., vol. 96 (1992), pp. 17-18
  • Werner, H., et al. "Spectroscopic and Chemical Characterization of Fullerene Black", Chem. Phys. Lett., vol. 194, #1,2 (1992), pp. 62-66
  • Ajayan, P., et al. "Opening Carbon Nanotubes With Oxygen and Implications for Filling", Nature, vol. 362, pp. 522-525 (Apr. 1993)
  • Iijima, S., et al. "Capillarity-induced Filling of Carbon Nanotubes", Nature, vol. 361, pp. 333-334 (Jan. 1993)
  • Ando, Y., et al. "Preparation of Carbon Nanotubes by Arc-Discharge Evaporation", Japan Journal of Applied Physics, vol. 32 (1993), Part 2, No. 1A/B, pp. L107-L109 (Jan. 1993
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