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Equilibrium production of sodium carbonate from sodium bicarbonate

Patent 5609838 Issued on March 11, 1997. Estimated Expiration Date: Icon_subject June 9, 2015. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

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Inventors

Assignee

Application

No. 489103 filed on 06/09/1995

US Classes:

423/206.1, Mixture contains organic or carbonaceous impurity423/206.2, Alkali carbonate from trona423/427By reacting a bicarbonate

Examiners

Primary: Langel, Wayne A.

Attorney, Agent or Firm

Foreign Patent References

  • 15822 GB 07/13/1892
  • 883202 GB 11/13/1961

International Class

C01D 007/37

Abstract

A process for producing sodium carbonate and other sodium-based chemicals from an aqueous solution containing sodium bicarbonate by contacting an aqueous solution of a bicarbonate-containing composition with a gas that is predominately other than carbon dioxide in an amount and for a time adequate to cause a sufficient amount of carbon dioxide to leave the aqueous solution to reduce the amount of bicarbonate ion in the solution by converting the bicarbonate to carbonate as carbon dioxide leaves the solution and thereafter converting the remaining solution to other sodium salts.

Other References

  • Sarbar, M., Covington, A., Nuttall, R. and Goldberg, R., "The Activity and Osmotic Coefficients of Aqueous Sodium Bicarbonate Solutions," J. Chem. Thermodynamics, 14, 967-76, 1982
  • Vanderzee, C., "Thermodynamic properties of Solutions of a Hydrolyzing Electrolyte: relative partial molar enthalpies . . . and solute activity coefficients of aqueous sodum carbonate," J. Chem Thermodynamics, 14, 1051-67, 1982
  • Butler, J. N., Carbon Dioxide Equilibria and Their Applications, Lewis Publishers, Chelsea, MI 1991
  • Garrett, D., Natural Soda Ash, Von Nostrand Reinhold, New York, NY, 1992, pp. 336-355
  • Harned, H. and Manweiler, G., "The Thermodynamics of Ionized Water in Sodium Chloride Solutions," 57, 1873-76, Oct. 1935
  • Yakovlev, V. A., Verkh, E. A. and Poltoratskii, G. M., "Constant of the Second-Stage of Dissociation of Carbonic Acid in Concentrated Solutions of Sodium Sulfate," Zh. Prikl. Khim (Leningrad), 62(6), 1365-6, 1989
  • Rao, D. P., "Design of Packed Towers for Absorption and Desportion of Carbon Dioxide Using Hot Promoted Potassium Carbonate Solution," Gas Separation & Purification, 5, 177-80, 1991
  • Pohorecki, R., and Kucharski, E., "Desportion with Chemical Reaction in the System CO2 -aqueous Solution of Potassium Carbonate," Chemical Engineering Journal, 46, 1-7, 1991
  • Peiper, J. and Pitzer, K., "Thermodynamics of Aqueous Carbonate Solutions Including Mixtures of Sodium Carbonate, Bicarbonate and Chloride," J. Chem. Thermodynamics, 14, 618-38 (1982)
  • Danckwerts, P. V. and Mahajani, V. V., "The Stripping of CO2 from Amine Promoted Potash Solutions at 100° C", Chemical Engineering Science, 38, 321-7, 1983
  • Nii, S., Iwata, T., Takahashi, K. and Takeuchi, H., "Regeneration of CO2 -Loaded Carbonate Solution by Reducing Pressure," J. Chem. Eng. of Japan, vol. 14, No. 2, 148-53, 1995
  • Taylor, E., "Thermodynamics of Sodium Carbonate in Solution," Institute of Paper Chemistry (rec'd Feb. 14, 1956), reprinted Jul., 1955, 653-57
  • Eickmeyer, A. G., "Carbon Dioxide Removal, IV, Catacarb", Fertilizer Science Technology Series, 2, 165-9, 1974
  • Savage, D., Astarita, G., and Joshi, S., "Chemical Absorption and Desorption of Carbon Dioxide from Hot Carbonate Solutions," Chemical Engineering Science, 35, 1513-22, 198
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