U.S. patents available from 1976 to present.
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Very low creep, ultra high modulus, low shrink, high tenacity polyolefin fiber having good strength retention at high temperatures and method to produce such fiber

Patent 5578374 Issued on November 26, 1996. Estimated Expiration Date: Icon_subject February 8, 2015. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3210452

3377329

3564835

Polymer materials
Patent #: 4268470
Issued on: 05/19/1981
Inventor: Capaccio ,   et al.

High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore
Patent #: 4413110
Issued on: 11/01/1983
Inventor: Kavesh ,   et al.

Stretched polyethylene filaments of high strength and high modulus, and their production
Patent #: 4617233
Issued on: 10/14/1986
Inventor: Ohta ,   et al.

Heat shrunk fabrics provided from ultra-high tenacity and modulus fibers and methods for producing same
Patent #: 4819458
Issued on: 04/11/1989
Inventor: Kavesh ,   et al.

Resin or rubber article reinforced with a polyolefin fiber having improved initial elongation
Patent #: 5143977
Issued on: 09/01/1992
Inventor: Yagi, et al.

Molecular orientation articles molded from high-molecular weight polyethylene and processes for preparing same
Patent #: 5252394
Issued on: 10/12/1993
Inventor: Kouno, et al.

Molecular orientation articles molded from high-molecular weight polyethylene and processes for preparing same Patent #: 5302453
Issued on: 04/12/1994
Inventor: Kouno, et al.

Inventors

Assignee

Application

No. 385238 filed on 02/08/1995

US Classes:

428/364, Rod, strand, filament or fiber428/394, Synthetic resin or polymer428/902HIGH MODULUS FILAMENT OR FIBER

Examiners

Primary: Ryan, Patrick
Assistant: Gray, J. M.

Attorney, Agent or Firm

Foreign Patent References

  • 0064167A1 EP 11/21/1982
  • 0139141A2 EP. 06/21/1984
  • 0110047A2 EP 06/21/1984
  • 0135253A1 EP 03/21/1985
  • 0213208 EP. 02/21/1986
  • 0205960A2 EP. 05/21/1986
  • 0205960B1 EP. 05/21/1986
  • 0187974A2 EP 07/21/1986
  • 52-647/85 JP. 03/21/1983
  • 59-216913 JP. 12/21/1984
  • 183099 NL. 11/21/1976
  • 1067142 GB. 03/21/1967
  • 2042414 GB. 02/21/1980

International Class

D02G 003/00

Abstract

By poststretching, at a temperature between about 135° and 160° C., a polyethylene fiber, which has already been oriented by drawing at a temperature within 5° C. of its melting point, an ultra high modulus, very low creep, low shrink, high tenacity polyolefin fiber having good strength retention at high temperatures is obtained. The poststretching can be in multiple stages and/or with previous annealing. The poststretching should be done at a draw rate of less than 1 second-1. Tensile modulus values over 2,000 g/d for multifilament yarn are consistently obtained for ultrahigh molecular weight-polyethylene, with tensile strength values above 30 g/d while at the same time dramatically improving creep (at 160° F. (71.1° C.) and 39,150 psi load) by values at least 25% lower than fiber which has not been poststretched. Shrinkage is improved to values less than 2.5% of the original length when heated from room temperature to 135° C. Performance at higher temperature is improved by about 15° to 25° C.

Other References

  • Plastics & Rubber Processing & Applications, vol. 1, No. 2, Routes to improved creep behaviour in drawn linear polyethylene by M. A. Wilding and I. M. Ward, pp. 167-172 (1981)
  • Applied Science Publishers, Ltd., Drawing and Hydrostatic Extrusion of Ultra-High Modulus Polymers by G. Capaccio, A. G. Gibson and I. M. Ward, pp. 54-59 (1977)
  • Zeit-Schriften-Schou, Translation: Polyethylene Fibres Could Beat Carbon; Brit. Plast. & Rubber, Jul./Aug. 1978, pp. 32-36
  • Makromol Chem. 182 (1981), "Hot Drawing of Surface Growth Polyethylene Fibers, 21" Effect of Drawing Temperature and Elongational viscosity by J. Smook, J. C. M. Torfs, A. Pennings, pp. 3351-3359
  • Hercules Technical Report 1900 UHMW Polymer Engineering Information (1978)
  • Developments in Oriented Polymers-2 edited by I. M. Ward, Dept. of Physics University of Leeds, UK (1987)
  • DSM Higher Performance Polyethylene Development Project Indroduction-Dyneema
  • Kirk-Othmer, Encyclopedia of Chemical Technology 3rd Edition, vol. 16, "Noise Pollution to Perfumes", pp. 357-38
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