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Process of isolating carbon nanotubes from a mixture containing carbon nanotubes and graphite particles

Patent 5560898 Issued on October 1, 1996. Estimated Expiration Date: Icon_subject August 1, 2014. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Process for separating mineral wool fibers from nonfibrous materials
Patent #: 4254823
Issued on: 03/10/1981
Inventor: Cederqvist ,   et al.

Uncapped and thinned carbon nanotubes and process Patent #: 5346683
Issued on: 09/13/1994
Inventor: Green, et al.

Inventors

Assignee

Application

No. 283508 filed on 08/01/1994

US Classes:

423/461, Recovery or purification423/445B, Fullerene (e.g., C60, C70, etc.)423/447.2Product

Examiners

Primary: Lewis, Michael
Assistant: DiMauro, P. T.

Attorney, Agent or Firm

International Classes

D01F 009/12
C01B 031/02

Foreign Application Priority Data

1993-08-04 JP

Abstract

Carbon nanotubes are isolated from a mixture containing the carbon nanotubes and graphite particles by a process including the steps of:finely pulverizing the mixture;dispersing the pulverized product in a liquid medium;centrifuging the resulting dispersion to obtain a supernatant containing carbon nanotubes and graphite particles having a particle size of 0.3 μm or less;separating the supernatant into a solid phase and a liquid phase; andcalcining the solid phase in an oxygen-containing atmosphere at a temperature sufficient to burn the graphite particles and to leave the nanotubes.

Other References

  • Pang, L. S. K., et al. "Thermogravimetric Analysis of Carbon Nanotubes and Nanoparticles", J. Phys. Chem., vol. 97, #27, pp. 6941-6942 (08 Jul. 1993)
  • Seraphin, S., et al. "Effect of Processing Conditions on the Morphology and Yield of Carbon Nanotubes", Carbon, vol. 31, #5, pp. 685-689 (1993, no month)
  • T. Ebbesen, et al. "Purification of Nanotubes", Nature, vol. 369, p. 519 (10 Feb. 1994)
  • Ajayan, P. M., et al. "Opening Carbon Nanotubes with Oxygen and Implications for Filling", Nature, vol. 362, pp. 522-525 (8 Apr. 1993)
  • Saito, Y., et al. "Growth and Structure of Graphitic Tubules and Polyhedral Particles . . . ", Chem. Phys. Lett; vol. 204, #3,4, pp. 277-282 (19 Mar. 1993)
  • Ebbesen, et al "Large-Scale Synthesis of Carbon Nanotubes," Nature, vol. 358, 16 Jul. 1992, pp. 220-22
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