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Clathrate freeze desalination apparatus and method

Patent 5553456 Issued on September 10, 1996. Estimated Expiration Date: Icon_subject May 17, 2015. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

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Inventor

Assignee

Application

No. 443384 filed on 05/17/1995

US Classes:

62/59, Accumulating holdover ice in situ62/123, SEPARATOR FOR SOLIDIFIED CONSTITUENT OF LIQUID MIXTURE62/532, Fractionally solidifying a constituent and separating the same62/533, Including direct contact with added refrigerant62/537Utilizing a constituent of the original mixture or solution as refrigerant

Examiners

Primary: Kilner, Christopher

Attorney, Agent or Firm

International Classes

B01D 009/04
F25D 003/00

Abstract

A clathrate freeze desalination system and method in which a clathrate forming agent is injected through a submerged pipeline to a predetermined ocean depth at which the surrounding ocean temperature is less than the clathrate forming temperature. The agent combines with the salt water to form a slurry of clathrate ice crystals and brine. The pipeline is concentric and coaxial with a surrounding outer pipeline in which the slurry is formed. The slurry is pumped back to the surface through the outer pipeline and the ice crystals are washed to remove brine. The washed crystals are then melted, and the resultant water is separated from the clathrate forming agent, which may be discarded or recycled for re-injection through the inner pipeline. The melting of the clathrate ice as well as the cold water and air circulating in the desalination plant can be utilized as a source of air conditioning for local buildings and facilities.

Other References

  • Vlahakis, John G. et al.,The Growth Rate of Ice Crystals: The Properties of Carbon Dioxide Hydrate: A Review of Properties of 51 Gas Hydrates Progress Report No.830, Syracuse, New York, Nov. 1972
  • Campbell, R. J. et al.,Gravity Wash Column Design, Procurement, and Installation; Followed by Development
  • Tests of the Modified Single-Stage Desalting Pilot Plant At Wrightsville Beach, North Carolina,AVCO Systems Division, Wilmington, Massachusetts, 1979
  • Barduhn, Allen J., "Desalination by Freezing Processes", Encyclopedia of Chemical Processing and Design,New York, New York and Basel, Switzerland, 1982
  • Burns and Roe Industrial Services Corporation, Absorption Freezing Vapor Compression(AFVC) 25,000 gpd, Paramus, New Jersey, Jan. 1982
  • Burns and Roe Industrial Services Corporation, Falling Film Indirect Freezing -6,000 gpd, Pramus, New Jersey, Jan. 1982
  • Wiegandt, Herbert, "Desalination by Freezing", Desalination Handbook, Ithaca, New York, Mar. 1990
  • Hahn, W. J., Present Status of the Office of Saline Water Freezing Process Program, Wrightsville Beach, North Carolina, (not dated
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