Glass cleaner compositions having good filming/streaking characteristics and substantive modifier to provide long lasting hydrophilicity
Patent 5534198 Issued on July 9, 1996. Estimated Expiration Date: January 25, 2015. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.
510/182, With aliphatic alcohol, ether, or ketone component510/181, Aqueous liquid composition510/400, With soil-release, anti-soiling, coating, or nonabrasive polishing component (e.g., with polysiloxane, chalk, etc.)510/427, With diverse non-soap surfactant510/434, Polycarboxylic acid component, or acid anhydride or salt thereof (e.g., acrylic acid polymer, maleic anhydride, sodium citrate, etc.)510/475, Synthetic polymer or natural rubber (other than polyether, such as polyethylene glycol, alkylene oxide condensation products, etc.)510/476, Carboxylic acid anhydride, free carboxyl group, or salt thereof in the polymer510/490Nitrogen attached indirectly to the carboxyl group by nonionic bonding, or salt thereof
Detergent compositions having good filming/streaking characteristics contain effective amounts of specific substantive materials to increase the hydrophilicity of the glass. Preferred formulas contain a amphoteric, including zwitterionic, and optionally, but preferably, anionic detergent surfactant at levels (e.g., from about 0.02 to about 15%); hydrophobic solvent; alkaline material, especially volatile alkaline materials comprising monoethanolamine or certain beta-amino-alkanol compounds; and salt of polycarboxylate, preferably polyacrylate, polymer at effective levels (e.g., from about 0.01% to about 10%, by weight of the composition).
Other References
Seko "Application of Polystyrene Sulfonate to Detergents" C.A. 27545r 1973 (no month available)
N. Parris et al., "Soap Based Detergent Formulations. V. Amphoteric Lime Soap Dispersing Agents," JAOCS, 50(1973) pp. 509-512
W. R. Noble et al., "Soap-Based Detergent Formulations: X. Nature of Detergent Deposits," JAOCS, 52(1975) pp. 1-4
N. Parris et al., "Soap-Based Detergent Formulations: XII. Alternate Syntheses of Surface Active Sulfobetaines," JAOCS, 53(1976) pp. 60-63
F. D. Smith et al., "Soap-Based Detergent Formulations: XV. Amino Esters of alpha-Sulfo Fatty Acids," JAOCS, 53(1976) pp. 69-72
Parris et al., "Soap-Based Detergent Formulations: XVII. Effect of Structure Variations on Surface-Active Properties of Sulfur Containing Amphoteric Surfactants", JAOCS, 53(1976) pp. 97-100
J. K. Weil et al., "Soap-Based Detergent Formulations: XX. The Physical and Chemical Nature of Lime Soap Dispersions," JAOCS, 53(1976) pp. 757-761
J. K. Weil et al., "The Mutual Solubilization of Soap and Lime Soap Dispersing Agents," JAOCS, 54(1977) pp. 1-3
T. J. Micich et al., "Soap-Based Detergent Formulations: XIX. Amphoteric Alkyl-Succinamide Derivatives as Lime Soap Dispersants," JAOCS, 54(1977) pp. 91-94
T. J. Micich et al., "Soap-Based Detergent Formulations: XXII. Sulfobetaine Derivatives of N-Alkylglutaramides and Adipamides," JAOCS, 54(1977) pp. 264-266
N. Parris et al. "Soap-Based Detergent Formulation: XXIV. Sulfobetaine Derivatives of Fatty Amides," JAOCS, 54(1977), pp. 294-296
J. K. Weil et al., "Surface Active Properties of Combinations of Soap and Lime Soap Dispersing Agents," JAOCS, 54(1976) pp.339-342
J. M. Kaminski et al., "Soap-Based Detergent Formulations: XXIII. Synthesis of p-Sulfobenzyl Ammonium inner Salts and Structural Correlation with Analogous Amphoterics," JAOCS, 54(1977) pp. 516-520
F. D. Smith et al., "Soap-Based Detergent Formulations: XXI. Amphoteric Derivatives of Fatty Amides of Aminoethylethanolamine," JAOCS, 55(1978) pp. 741-744
J. M. Kaminski et al., "Soap-Based Detergent Formulations: XXV. Synthesis and Surface Active Properties of Higher Molecular Weight Betain Lime Soap Dispersants," JAOCS, 56(1979) pp. 771-774
W. M. Linfield, "Soap and Lime Soap Dispersants," JAOCS, 55(1978), pp. 87-92
W. R. Noble et al., "Soap-Based Detergent Formulations: XXVI. Hard Water Detergency of Soap-Lime Soap Dispersant Combinations with Builders and Inorganic Salts," JAOCS, 57(1980), pp. 368-372
J. G. Weers et al., "Effect of the Intramolecular charge separation distance on the solution properties of betaines and sulfobetaines," Langmuir, 1991, vol. 7(5), pp. 854-867. (Abstract Only)
T. Takeda et al., "Synthesis and properties of a w-bis(amidopropylhydroxysulfobetain)-type amphoteric surfactants," Yukagaku, 1990, vol. 39(8), pp. 576-579. (Abstract Only)
Chem. Abstract 102(22): 190818t-P. Busch et al., "Hair-conditioning effect of quar hydroxypropyl-trimethylammonium chloride. Part I," Parfuem. Kosmet. 1984, 65(11), 692, 694-6, 698
Chem. Abstract 192(22): 190819u-P. Busch et al., "Hair-conditioning effec of quar hydroxypropyl-trimethylammonium chloride. Part II." Parfuem. Kosmet. 1984, 65(12), 756, 758-60
Chem. Abstract 108(1):5366g--C. A. Bunton, "Micellar effects on nucleophilicity," Adv. Chem. Ser. 1987, 215(Nucleophility), 425-41
Chem. Abstract 115(6): 56929v--CTFA, Inc., "Final report on the safety assessment of cocamidopropyl betain," J. Am. Coll. Toxicol. 1991, 10(1). 33-52
Chem. Abstract 115(14): 138653q--V. Allikmaa, "Highly efficient reversed-phase HPLC studies of amphoteric and cationic amido group containing surfactants," Eesti Tead. Akad. Toim., Keem 1991, 40(1), 67-72
Soap-Based Detergent Formulations: XII. "Alternate Syntheses of Surface Active Sulfobetaines", Parris et al., J. Amer. Oil Chem. Soc., vol. 53, Feb. 1976, pp. 60-63
Zwitterionic Surfactants: Structure and Performance, Fernly, Journal of The Oil Chemists' Society, vol. 55, Jan. 1978, pp. 98-103
Chem. Abstract 113(21):188305g--Schmidt et al., Z. Naturforsch., C: Biosci., 45(6) 729-32, "Short-wavelength absorbing complexes of chlorophyll in a micellar solution of cationic detergents."
Chem. Abstract 116(4):131640v--A. Domsch, REWO; "Amphoteric surfactants in detergents and cleaning products," Comun. Jorn. Com. Esp. Deterg., 22, 223-41
Brochure: "Soap Scum Removal Using Varion.RTM. AM-V," Robert Pifer and James Denison, Sherex Chemical Co., Inc., Form No. 10/91, 199