U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Method for altering flow profile of a subterranean formation during acid stimulation

Patent 5529122 Issued on June 25, 1996. Estimated Expiration Date: Icon_subject December 15, 2014. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

3410344

3583483

3612179

3612182

Foamed acids stabilized with alkanols
Patent #: 4235734
Issued on: 11/25/1980
Inventor: Scherubel

Highly stable alcohol foams and methods of forming and using such foams
Patent #: 4440653
Issued on: 04/03/1984
Inventor: Briscoe ,   et al.

Oil recovery process
Patent #: 4612991
Issued on: 09/23/1986
Inventor: Shaw

Oil recovery composition
Patent #: 4732690
Issued on: 03/22/1988
Inventor: Shaw

Multipurpose aqueous foamer
Patent #: 4796702
Issued on: 01/10/1989
Inventor: Scherubel

Process for improving the gas sweeping of an oil formation, using foams mainly containing surfactants with perfluoric groups
Patent #: 4836281
Issued on: 06/06/1989
Inventor: Robin ,   et al.

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Inventor

Assignee

Application

No. 356608 filed on 12/15/1994

US Classes:

166/281, Separate steps of (1) cementing, plugging or consolidating and (2) fracturing or attacking formation166/307, Attacking formation166/309, Producing foam or gas in well by foaming or gas producing material507/202, Contains intended gaseous phase at entry into wellbore507/205, Organic component contains fluorine bonded directly to carbon507/211, Carbohydrate is polysaccharide507/261Organic component contains ether linkage (e.g., PEG ether, etc.)

Examiners

Primary: Suchfield, George A.

Attorney, Agent or Firm

International Class

E21B 043/27

Abstract

A method for acidizing a subterranean formation wherein a specific foam is used to block flow through the higher-permeable zones of the formation while the acid is being injected therein. The foam is generated from a surfactant solution comprised of a blend of surfactants comprised of a nonionic primary surfactant (e.g. ethoxylated alcohol or polyglycosides) a cationic co-surfactant (e.g. fluorinated quaternary ammonium chloride). A polymer (e.g. polysaccharides or partially hydrolyzed polyacrylamide) may be added to the surfactant solution to enhance the foam mobility reduction and a co-solvent (e.g. polyol) may be added if necessary to maintain the surfactant/polymer complex in solution.

Other References

  • "Mobility Control Using CO2 Forms (sic)"; S. H. Yang et al; SPE 19689 (Society of Petr. Engr); San Antonio, TX; Oct. 8-11, 1989
  • "Applying Fractional-Flow Theory to Foams for Diversion in Matrix Acidization" Z. H. Zhou et al; SPE 24660; Washington, DC Oct. 4-7, 199
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