U.S. patents available from 1976 to present.
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Method and apparatus for generating, transporting and dissociating gas hydrates

Patent 5473904 Issued on December 12, 1995. Estimated Expiration Date: Icon_subject November 12, 2013. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

2270016

2356407

2375559

3217503

3514274

Transportation of natural gas as a hydrate
Patent #: 3975167
Issued on: 08/17/1976
Inventor: Nierman

Storage of fuel gas
Patent #: 4147456
Issued on: 04/03/1979
Inventor: Klass

Gasified ice product and process having improved storage stability
Patent #: 4347707
Issued on: 09/07/1982
Inventor: Zemelman ,   et al.

Quiescent formation of gasified ice product and process
Patent #: 4393660
Issued on: 07/19/1983
Inventor: Kleiner ,   et al.

Gasified ice process and product
Patent #: 4404807
Issued on: 09/20/1983
Inventor: Zemelman ,   et al.

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Inventors

Assignee

Application

No. 152302 filed on 11/12/1993

US Classes:

62/46.1, With sorbing or mixing62/46.2, Mixing of substance with hydrogen62/59, Accumulating holdover ice in situ585/15HYDRATE OR PRODUCTION THEREOF

Examiners

Primary: Kilner, Christopher

Attorney, Agent or Firm

International Class

F17C 011/00

Abstract

Methods and apparatus for generating, transporting and dissociating gas hydrates are disclosed. The preferred apparatus includes a mobile tank initially containing liquid water. Compressed hydrate-forming gas is combined in a pipe with the liquid water under locally supercooled conditions. The formed gas hydrate is blown into the mobile tank for transport and eventual consumption.

Other References

  • M. Burshears, et al., "A Multi-Phase, Multi-Dimensional, Variable Composition Simulation of Gas Production From a Conventional Gas Reservoir in Contact With Hydrates," Presentation at the Unconventional Gas Technology Symposium of the Society of Petroleum Engineers held in Louisville, Ky., May 18-21, 1986 (SPE 15246, pp. 449-456)
  • K. Domionic, et al., "Gas Production From Depressurization of Bench-Scale Methane Hydrate Reservoirs," U.S. Department of Energy, DOE/METC-87/4073, pp. 1-9, Mar. 1987
  • G. B. Guo, et al., "Gas Hydrates Decomposition and Its Modeling," 1992 International Gas Research Conference, New Mexico Institute of Mining and Technology (1992)
  • G. D. Holder, et al., "Simulation of Gas Production From a Reservoir Containing Both Gas Hydrates and Free Natural Gas," Presentation at the 57th Annual Fall Technical Conference and Exhibition of the Society of Petroleum Engineers of AIME held in New Orleans, La., Sep. 26-29, 1982 (SPE 11105, pp. 1-6)
  • V. A. Kamath, et al., "Dissociation Heat Transfer Characteristics of Methane Hydrates," AIChE Journal, vol. 33, No. 2, pp. 347-350, Feb. 1987
  • V. A. Kamath, et al., "Evaluation of Hot-Brine Stimulation Technique for Gas Production From Natural Gas Hydrates," Journal of Petroleum Technology, pp. 1379-1388, Nov. 1987
  • V. A. Kamath, et al., "Experimental Study of Brine Injection and Depressurization Methods for Dissociation of Gas Hydrates, " Presentation at the 64th Annual Technical Conference and Exhibition of the Society of Petroleum Engineers held in San Antonio, Tex., Oct. 8-11, 1989, (SPE 19810, pp. 1-10
  • V. A. Kamath, et al., "Three Phase Interfacial Heat Transfer During the Dissociation of Propane Hydrates," Chemical Engineering Science, vol. 39, No. 10, pp. 1435-1442, 1984
  • H. C. Kim, et al., "Kinetics of Methane Hydrate Decomposition," Chemical Engineering Science, vol. 42, No. 7, pp. 1645-1653, 1987
  • P. L. McGuire, "Methane Hydrate Gas Production: An Assessment of Conventional Production Technology as Applied to Hydrate Gas Recovery," Los Alamos National Laboratory, pp. 1-17, Nov. 1981, LA-9102-MS
  • M. S. Selim, et al., "Hydrate Dissociation in Sediment," Presentation at the 62nd Annual Technical Confernece and Exhibition of the Society of Petroleum Engineers held in Dallas, Tex., Sep. 27-30, 1987, (SPE 16859, pp. 243-258)
  • M. S. Selim, et al., "Modeling of the Dissociation of an In-Situ Hydrate," Presentation at the SPE 1985 California Regional Meeting held in Bakersfield, Calif., Mar. 27-29, (SPE 13597, pp. 75-80)
  • E. D. Sloan, Jr., "Clathrate Hydrates of Natural Gases," Marcel Dekker, Inc., pp. 12-16, 1990
  • J. W. Ullerich, et al., "Theory and Measurement of Hydrate Dissociation," AIChE Journal, vol. 33, No. 5, pp. 747-752, May 1987
  • M. H. Yousif, et al., "Experimental and Theoretical Investigation of Methane Gas Hydrate Dissociation in Porous Media," Presentation at the 63rd Annual Technical Conference and Exhibition of the Society of Petroleum Engineers held in Houston, Tex., Oct. 2-5, 1988 (SPE 18320, pp. 571-583
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