U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Methanol production process using a high nitrogen content synthesis gas with a hydrogen recycle

Patent 5472986 Issued on December 5, 1995. Estimated Expiration Date: Icon_subject November 8, 2014. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Utilization of low BTU natural gas
Patent #: 4093029
Issued on: 06/06/1978
Inventor: Weisz, et al.

Process for methanol production
Patent #: 4181675
Issued on: 01/01/1980
Inventor: Makin ,   et al.

Process for producing methanol from a feed gas
Patent #: 4650814
Issued on: 03/17/1987
Inventor: Keller

Process for the production of methanol
Patent #: 5063250
Issued on: 11/05/1991
Inventor: Murayama, et al.

Methanol production
Patent #: 5079267
Issued on: 01/07/1992
Inventor: Kao, et al.

Methanol synthesis
Patent #: 5173513
Issued on: 12/22/1992
Inventor: Pinto

Process for recovering natural gas in the form of a normally liquid carbon containing compound
Patent #: 5177114
Issued on: 01/05/1993
Inventor: Van Dijk, et al.

Process for producing and utilizing an oxygen enriched gas Patent #: 5245110
Issued on: 09/14/1993
Inventor: Van Dijk, et al.

Inventor

Application

No. 336298 filed on 11/08/1994

US Classes:

518/705, TREATMENT OF FEED OR RECYCLE STREAM518/703, Gaseous oxygen utilized in the preliminary reaction518/704Water utilized in the preliminary reaction

Examiners

Primary: Lone, Werren B.

Attorney, Agent or Firm

International Class

C07C 027/00

Abstract

A method for preparing methanol from a synthesis gas having less than 90% the stoichiometric amount of H2 to convert the CO and CO2 content of the synthesis gas to methanol by recycling into combination with such synthesis gas a sufficient amount of a hydrogen rich gas stream obtained as a permeate gas by diffusion of the process tail gas to provide a combined synthesis-recycle gas stream having at least about 95% of the stoichiometric amount of H2 to convert its CO and CO2 content to methanol. In a preferred embodiment of the invention compressed air is taken from a gas turbine to form the oxidant steam used in forming the synthesis gas, such synthesis gas in combination with the hydrogen rich recycle gas is processed through a series of methanol convertors to methanol and the non-permeate portion of the tail gas from this methanol process is returned as fuel to the gas turbine.

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