U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Method of producing a glycolic acid ester

Patent 5455372 Issued on October 3, 1995. Estimated Expiration Date: Icon_subject March 10, 2014. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Process for the preparation of ethylene glycol
Patent #: 4112245
Issued on: 09/05/1978
Inventor: Zehner ,   et al.

Process for the production of glycollic acid esters
Patent #: 4409395
Issued on: 10/11/1983
Inventor: Miyazaki ,   et al.

Process for producing ethylene glycol and/or glycolic acid ester, catalyst composition used therefor, and process for production thereof Patent #: 4585890
Issued on: 04/29/1986
Inventor: Miyazaki ,   et al.

Inventors

Assignee

Application

No. 209386 filed on 03/10/1994

US Classes:

560/179Oxy in acid moiety

Examiners

Primary: Dees, Jose G.
Assistant: Frazier, Barbara S.

Attorney, Agent or Firm

Foreign Patent References

  • 0057007 EP. 08/13/1982
  • 2031883 GB. 02/13/1983

International Class

C07C 069/675

Foreign Application Priority Data

1993-03-12 JP

Abstract

A glycolic acid ester is produced by hydrogenating an oxalic acid diester of the formula, (COOR)2, wherein R is a C1-6 alkyl group, with hydrogen in the presence of a solid catalyst comprising, for example, copper and silver metals carried on a solid carrier, and in the additional presence of an aliphatic alcohol, and collecting the resultant glycolic acid ester from the reaction mixture by distillation, preferably in the presence of an ester of a C3-12 dicarboxylic acid.

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