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Protecting carbon steel from corrosion with nonconducting poly(aniline)

Patent 5441772 Issued on August 15, 1995. Estimated Expiration Date: Icon_subject September 29, 2013. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

Electrochemistry employing polyaniline
Patent #: 4820595
Issued on: 04/11/1989
Inventor: MacDiarmid ,   et al.

Conductive polymer-polyimide blends and method for producing same
Patent #: 4855361
Issued on: 08/08/1989
Inventor: Yaniger ,   et al.

Solution processible forms of electrically conductive polyaniline and the method of manufacture of electroconductive articles therefrom
Patent #: 5006278
Issued on: 04/09/1991
Inventor: Elsenbaumer

Electrically conductive polymer material having conductivity gradient
Patent #: 5162135
Issued on: 11/10/1992
Inventor: Gregory, et al.

Method for enhancing polyaniline conductivity
Patent #: 5176851
Issued on: 01/05/1993
Inventor: Barry, Jr.

Process for forming conjugated backbone block copolymers
Patent #: 5227092
Issued on: 07/13/1993
Inventor: Han

Electromagnetic radiation absorbers and modulators comprising polyaniline Patent #: 5294694
Issued on: 03/15/1994
Inventor: Epstein, et al.

Inventors

Assignee

Application

No. 129699 filed on 09/29/1993

US Classes:

427/388.1, Metal base427/386, Epoxy or polyepoxide containing coating427/388.2Cross-linked or infusible coating

Examiners

Primary: Dudash, Diana

Attorney, Agent or Firm

International Class

B05D 007/14

Abstract

Carbon steel substrates are protected from corrosive environments by a coating of nonconductive poly(aniline) which has been chemically prepared and cast onto the substrate from solution. The coating can also include other polymers which are miscible with the poly(aniline) but do not protonate it so as to make it conductive. Such polymers can include polyimides, epoxies, and urethane linked diisocyanates, among others. In these blends, a weight composition of at least 5% poly(aniline) to the other polymer is preferred. Overall, the nonconductive form of polyaniline has been found to be more effective in this service than the conductive form. Air oxidation of the poly(aniline) coating before exposure to a corrosive environment enhances the benefits.

Other References

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  • D. W. DeBerry, "Modification of the Electrochemical and Corrosion Behavior of Stainless Steels with an Electroactive Coating", Selectro. Chem., Electrochemical Science and Technology, (1985) p. 1022 no month available
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