U.S. patents available from 1976 to present.
U.S. patent applications available from 2005 to present.

Method of making a rechargeable manganese-oxide compound and related electrode material

Patent 5419986 Issued on May 30, 1995. Estimated Expiration Date: Icon_subject October 15, 2013. Estimated Expiration Date is calculated based on simple USPTO term provisions. It does not account for terminal disclaimers, term adjustments, failure to pay maintenance fees, or other factors which might affect the term of a patent.

Patent References

1293463

3533740

3535217

3773916

Oxygen electrode and process for making the same
Patent #: 3948684
Issued on: 04/06/1976
Inventor: Armstrong

Process for making manganese dioxide
Patent #: 4006217
Issued on: 02/01/1977
Inventor: Faber ,   et al.

Process for producing electrolytic MnO2 from molten manganese nitrate hexahydrate
Patent #: 4048027
Issued on: 09/13/1977
Inventor: Senderoff

Manganese dioxide electrodes
Patent #: 4072586
Issued on: 02/07/1978
Inventor: De Nora ,   et al.

Process for producing a positive electrode for a non-aqueous cell
Patent #: 4133856
Issued on: 01/09/1979
Inventor: Ikeda ,   et al.

Production of electrolytic manganese dioxide
Patent #: 4170527
Issued on: 10/09/1979
Inventor: Beer ,   et al.

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Inventors

Assignee

Application

No. 137577 filed on 10/15/1993

US Classes:

429/224, Manganese component is active material423/50, Forming insoluble substance in liquid423/87, Group VA metal or arsenic (Sb, Bi, or As)423/599Manganese (e.g., manganate, etc.)

Examiners

Primary: Kalafut, Stephen

Attorney, Agent or Firm

Foreign Patent References

  • 0138316 EP. 04/13/1985
  • 51-6821 JP. 01/13/1976
  • 52-41846 JP. 03/13/1977
  • 1466 JP. 01/13/1981
  • 1038463 GB. 08/13/1966

International Class

H01M 004/50

Abstract

A method of making a rechargeable battery electrode material containing manganese oxide is provided. The method includes preparing an aqueous solution of manganese nitrate and dissolving bismuth nitrate into the solution. The mixture is heated to evaporate the water contained in the mixture and is further heated to facilitate decomposition of the nitrates in the mixture to form a compound containing manganese oxide and bismuth oxide. The compound is maintained at a temperature of between about 200 to 300 degrees Celsius for an additional 12 hours. Thereafter, the compound is cooled and ground to a desired particle size for use as a rechargeable battery electrode material. The compound may alto be mixed with commercially prepared electrolytic or chemical manganese dioxide to obtain a highly rechargeable battery electrode material. A related battery cell is also disclosed.

Other References

  • K. Kordesh, et al., Electrochemical Acta, 26, 1495 (1981). (Month N/A)
  • Wroblowa, et al., Journal of Electroanalytical Chemistry, 238, 93 (1987) (Month N/A)
  • Application serial No. 07/507980 Apr. 11, 1990 Appleb
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